化学通报(网络版)
化學通報(網絡版)
화학통보(망락판)
Chemistry Online
2008年
1期
,共1页
常雪灵%杨亚江%杨祥良*%马永梅
常雪靈%楊亞江%楊祥良*%馬永梅
상설령%양아강%양상량*%마영매
有机凝胶%模板诱导%纳米材料
有機凝膠%模闆誘導%納米材料
유궤응효%모판유도%납미재료
Organogel%Induced template%Nano-structural material
利用溶胶-凝胶聚合过程人工模拟生物矿化进程的技术,已经融入无机材料和超分子有机化学的研究领域.小分子有机凝胶因子在溶剂中发生自组装,形成多种形态的有机凝胶超分子结构,以其为模板,经过溶胶-凝胶过程,可以诱导转录形成各种形态的纳米材料.本文介绍了,利用有机凝胶因子自组装结构为模板,制备形态可控无机材料的研究进展及模板结构诱导转录的两种可能机制.
利用溶膠-凝膠聚閤過程人工模擬生物礦化進程的技術,已經融入無機材料和超分子有機化學的研究領域.小分子有機凝膠因子在溶劑中髮生自組裝,形成多種形態的有機凝膠超分子結構,以其為模闆,經過溶膠-凝膠過程,可以誘導轉錄形成各種形態的納米材料.本文介紹瞭,利用有機凝膠因子自組裝結構為模闆,製備形態可控無機材料的研究進展及模闆結構誘導轉錄的兩種可能機製.
이용용효-응효취합과정인공모의생물광화진정적기술,이경융입무궤재료화초분자유궤화학적연구영역.소분자유궤응효인자재용제중발생자조장,형성다충형태적유궤응효초분자결구,이기위모판,경과용효-응효과정,가이유도전록형성각충형태적납미재료.본문개소료,이용유궤응효인자자조장결구위모판,제비형태가공무궤재료적연구진전급모판결구유도전록적량충가능궤제.
The design of artificial models of “biomineralization” processes utilizing sol-gel polymerization has become a research branch of inorganic materials research and supramolecular organic chemistry. The self-assembled superstructures of low molecular weight organic gelators are used as versatile building blocks in organogels and as templates for sol-gel transcription into nano-structural materials. The use of self-assembled organic superstructures in the creation of novel inorganic materials with controlled morphologies is focused on and two mechanisms for forming nano-structural materials by the template method are illustrated in this paper.