化学通报（网络版）
化學通報（網絡版）
화학통보（망락판）
Chemistry Online
2010年
1期
1-11
,共11页
邵立东%胡敏奇%翟玲玲%毕韵梅*
邵立東%鬍敏奇%翟玲玲%畢韻梅*
소립동%호민기%적령령%필운매*
环三膦腈%星形高分子%树形高分子%合成%应用
環三膦腈%星形高分子%樹形高分子%閤成%應用
배삼련정%성형고분자%수형고분자%합성%응용
Cyclotriphosophazene%Star-shaped polymers%Dendritic polymers%Synthesis%Applications
综述了近十多年来以环三膦腈为核的非线性聚膦腈高分子的合成、性能及其应用.重点介绍了直接亲核取代法与多官能团引发剂法在合成以环三膦腈为核的星形高分子中的应用,以及发散法与收敛法在合成以环三膦腈为核的树形高分子中的应用.简要阐述了以环三膦腈为核的星形、树形高分子在光电材料、生物医用材料等方面的应用,并展望了以环三膦腈为核的非线性聚膦腈高分子的发展趋势和方向.
綜述瞭近十多年來以環三膦腈為覈的非線性聚膦腈高分子的閤成、性能及其應用.重點介紹瞭直接親覈取代法與多官能糰引髮劑法在閤成以環三膦腈為覈的星形高分子中的應用,以及髮散法與收斂法在閤成以環三膦腈為覈的樹形高分子中的應用.簡要闡述瞭以環三膦腈為覈的星形、樹形高分子在光電材料、生物醫用材料等方麵的應用,併展望瞭以環三膦腈為覈的非線性聚膦腈高分子的髮展趨勢和方嚮.
종술료근십다년래이배삼련정위핵적비선성취련정고분자적합성、성능급기응용.중점개소료직접친핵취대법여다관능단인발제법재합성이배삼련정위핵적성형고분자중적응용,이급발산법여수렴법재합성이배삼련정위핵적수형고분자중적응용.간요천술료이배삼련정위핵적성형、수형고분자재광전재료、생물의용재료등방면적응용,병전망료이배삼련정위핵적비선성취련정고분자적발전추세화방향.
The development of synthesis, properties and applications of nonlinear polymers with cyclotriphosophazene core were introduced. The synthetic methods of star-shaped and dendritic cyclotriphosophazene polymers including directly nucleophilic substituent, multiple functional group, divergent and convergent methods were discussed. The applications of star-shaped and dendritic polymers with cyclotriphosophazene core in photoelectric materials, biomaterials etc were briefly introduced and the prospect of nonlinear polymers with cyclotriphosophazene core was anticipated.
