CAJ | 학술논문

离子液体(ILs)因其独特物理化学性质成为新型反应溶剂和催化剂,在生物催化反应中有着广阔的应用前景.根据不同 ILs 的水溶性,其与水可形成4种反应介质,即微水 ILs 单相体系、亲水性 ILs-水单相体系、疏水性 ILs-水两相体系和 ILs 微乳液体系.本文分别介绍了不同 ILs 反应体系中生物催化剂的催化活性、稳定性和选择性,综述了这些体系中的生物催化反应研究进展.
리자액체(ILs)인기독특물이화학성질성위신형반응용제화최화제,재생물최화반응중유착엄활적응용전경.근거불동 ILs 적수용성,기여수가형성4충반응개질,즉미수 ILs 단상체계、친수성 ILs-수단상체계、소수성 ILs-수량상체계화 ILs 미유액체계.본문분별개소료불동 ILs 반응체계중생물최화제적최화활성、은정성화선택성,종술료저사체계중적생물최화반응연구진전.
Ionic liquids (ILs) are new reaction mediums and catalysts for biocatalytic reaction due to their excellent physical and chemical characteristics. ILs can form 4 kinds of reaction mediums with water based on their water solubility, that is, nearly anhydrous ILs systems, hydrophilic ILs-water systems, hydrophobic ILs-water two-phase systems, and water-in-ILs microemulsions. In this article, the activity, stability and selectivity of biocatalysts in the four ILs-containing mediums are summarized and the research progresses of biocatalytic reaction in the systems are discussed.