海洋科学
海洋科學
해양과학
MARINE SCIENCES
2013年
2期
7-11
,共5页
张一%李晓明%尚卓%李春顺%王斌贵
張一%李曉明%尚卓%李春順%王斌貴
장일%리효명%상탁%리춘순%왕빈귀
红树林%根际土壤%新化合物%次生代谢产物
紅樹林%根際土壤%新化閤物%次生代謝產物
홍수림%근제토양%신화합물%차생대사산물
Mangrove%rhizosphere%novel compound%secondary metabolites
对采自海南文昌红树林根际土壤样品中分离到的真菌Penicillium sp. MA-37的次生代谢产物的化学成分进行了研究.利用硅胶柱层析、葡聚糖凝胶Sephadex LH-20柱层析、制备薄层层析以及重结晶等分离方法并通过现代波谱技术共分离、鉴定了8个天然产物,分别为:氮-(2-甲氧基-4-羟基苯)-丙酰胺酸(1),氮-(2,4-二甲氧基苯)-丙酰胺酸(2),氮-(2,4-二甲氧基苯)-丙酰胺酸甲酯(3),(22E,24R)-麦角甾-5,7,22-三烯-3β-醇(4),(22E,24R)-麦角甾-4,6,8(14),22-四烯-3-酮(5),(22E,24R)-5α,8α-环二氧麦角甾-6,22-双烯-3β-醇(6), asperamide B (7), cis-4-hydroxy-6-deoxyscytalone (8);其中化合物1为新化合物,化合物2和3为新天然产物.
對採自海南文昌紅樹林根際土壤樣品中分離到的真菌Penicillium sp. MA-37的次生代謝產物的化學成分進行瞭研究.利用硅膠柱層析、葡聚糖凝膠Sephadex LH-20柱層析、製備薄層層析以及重結晶等分離方法併通過現代波譜技術共分離、鑒定瞭8箇天然產物,分彆為:氮-(2-甲氧基-4-羥基苯)-丙酰胺痠(1),氮-(2,4-二甲氧基苯)-丙酰胺痠(2),氮-(2,4-二甲氧基苯)-丙酰胺痠甲酯(3),(22E,24R)-麥角甾-5,7,22-三烯-3β-醇(4),(22E,24R)-麥角甾-4,6,8(14),22-四烯-3-酮(5),(22E,24R)-5α,8α-環二氧麥角甾-6,22-雙烯-3β-醇(6), asperamide B (7), cis-4-hydroxy-6-deoxyscytalone (8);其中化閤物1為新化閤物,化閤物2和3為新天然產物.
대채자해남문창홍수림근제토양양품중분리도적진균Penicillium sp. MA-37적차생대사산물적화학성분진행료연구.이용규효주층석、포취당응효Sephadex LH-20주층석、제비박층층석이급중결정등분리방법병통과현대파보기술공분리、감정료8개천연산물,분별위:담-(2-갑양기-4-간기분)-병선알산(1),담-(2,4-이갑양기분)-병선알산(2),담-(2,4-이갑양기분)-병선알산갑지(3),(22E,24R)-맥각치-5,7,22-삼희-3β-순(4),(22E,24R)-맥각치-4,6,8(14),22-사희-3-동(5),(22E,24R)-5α,8α-배이양맥각치-6,22-쌍희-3β-순(6), asperamide B (7), cis-4-hydroxy-6-deoxyscytalone (8);기중화합물1위신화합물,화합물2화3위신천연산물.
From the fermentation culture of strain Penicillium sp. MA-37 derived from mangrove rhizosphere, eight compounds were isolated by separation techniques including column chromatography with silica gel and Sephadex LH-20, preparative TLC and re-crystallization. Structures of all purified compounds were elucidated by analysis of their spectroscopic data to be N-(2-methoxy-4-hydroxyphenyl)-malonamic acid (1), N-(2,4-dimethoxyphenyl)-malonamic acid (2), N-(2,4-dimethoxyphenyl)-malonamic acid methyl ester (3), (22E,24R)-ergosta-5,7,22-trien-3β-ol (4), (22E,24R)-Ergosta-4,6,8(14),22-tetraen-3-one (5), (22E,24R)-5α,8α-epidioxyergosta-6,22-dien-3β-ol (6), asperamide B (7), cis-4-hydroxy-6-deoxyscytalone (8). Compound 1 was a new compound, while compounds 2 and 3 were reported as natural products for the first time.