江西师范大学学报(自然科学版)
江西師範大學學報(自然科學版)
강서사범대학학보(자연과학판)
JOURNAL OF JIANGXI NORMAL UNIVERSITY
2012年
6期
562-564
,共3页
贾晓丽%王强%宫晓瑞%赵三虎
賈曉麗%王彊%宮曉瑞%趙三虎
가효려%왕강%궁효서%조삼호
咔唑%1-氯-4-硝基苯%席夫碱%还原%合成
咔唑%1-氯-4-硝基苯%席伕堿%還原%閤成
잡서%1-록-4-초기분%석부감%환원%합성
carbazole%1-chloro-4-nitrobenzene%Schiff base%reduction%synthesis
以咔唑为起始原料,经Friedel-Crafts烷基化、Ullmann偶联、还原和胺醛缩合系列反应,合成了2个结构新颖的含咔唑结构单元的席夫碱类化合物,所得目标产物及中间体结构经1H NMR、13C NMR和IR 光谱确认.
以咔唑為起始原料,經Friedel-Crafts烷基化、Ullmann偶聯、還原和胺醛縮閤繫列反應,閤成瞭2箇結構新穎的含咔唑結構單元的席伕堿類化閤物,所得目標產物及中間體結構經1H NMR、13C NMR和IR 光譜確認.
이잡서위기시원료,경Friedel-Crafts완기화、Ullmann우련、환원화알철축합계렬반응,합성료2개결구신영적함잡서결구단원적석부감류화합물,소득목표산물급중간체결구경1H NMR、13C NMR화IR 광보학인.
With carbazole as starting material, two novel structure Schiff base containing carbazole moiety were synthesized through a serious of reaction such as Friedel-Crafts alkylation, Ullmann coupling, reduction and con-densation reaction.The structures of object products and intermediates were confirmed by 1H NMR , 13C NMR and IR spectrum.
