物理化学学报
物理化學學報
물이화학학보
ACTA PHYSICO-CHIMICA SINICA
2013年
2期
287-292
,共6页
周阳%褚有群%刘委明%马淳安*
週暘%褚有群%劉委明%馬淳安*
주양%저유군%류위명%마순안*
直接甲醇燃料电池%碳纳米管%三氧化钨%电催化
直接甲醇燃料電池%碳納米管%三氧化鎢%電催化
직접갑순연료전지%탄납미관%삼양화오%전최화
Direct methanol fuel cel%Carbon nanotube%Tungsten trioxide%Electro-catalysis
采用表面修饰技术将碳纳米管(CNT)表面羧基化,通过羧基将钨离子基团修饰到碳纳米管的外表面,再通过高温焙烧处理将钨离子基团氧化成WO3,成功合成了纳米WO3/CNT复合物,进一步还原Pt的前驱体而得到Pt-WO3/CNT复合催化剂.采用X射线粉末衍射(XRD)和透射电镜(TEM)对样品的形貌和晶型结构进行了表征,结果表明, Pt纳米粒子为面心立方晶体结构,均匀地分布在WO3修饰的碳纳米管表面.采用循环伏安(CV)和计时电流法研究了在酸性溶液中Pt-WO3/CNT催化剂对甲醇的电催化氧化活性,结果表明WO3修饰的碳纳米管载铂催化剂比用混酸处理的碳纳米管载铂催化剂对甲醇呈现出更高的电催化氧化活性和更好的稳定性.
採用錶麵脩飾技術將碳納米管(CNT)錶麵羧基化,通過羧基將鎢離子基糰脩飾到碳納米管的外錶麵,再通過高溫焙燒處理將鎢離子基糰氧化成WO3,成功閤成瞭納米WO3/CNT複閤物,進一步還原Pt的前驅體而得到Pt-WO3/CNT複閤催化劑.採用X射線粉末衍射(XRD)和透射電鏡(TEM)對樣品的形貌和晶型結構進行瞭錶徵,結果錶明, Pt納米粒子為麵心立方晶體結構,均勻地分佈在WO3脩飾的碳納米管錶麵.採用循環伏安(CV)和計時電流法研究瞭在痠性溶液中Pt-WO3/CNT催化劑對甲醇的電催化氧化活性,結果錶明WO3脩飾的碳納米管載鉑催化劑比用混痠處理的碳納米管載鉑催化劑對甲醇呈現齣更高的電催化氧化活性和更好的穩定性.
채용표면수식기술장탄납미관(CNT)표면최기화,통과최기장오리자기단수식도탄납미관적외표면,재통과고온배소처리장오리자기단양화성WO3,성공합성료납미WO3/CNT복합물,진일보환원Pt적전구체이득도Pt-WO3/CNT복합최화제.채용X사선분말연사(XRD)화투사전경(TEM)대양품적형모화정형결구진행료표정,결과표명, Pt납미입자위면심립방정체결구,균균지분포재WO3수식적탄납미관표면.채용순배복안(CV)화계시전류법연구료재산성용액중Pt-WO3/CNT최화제대갑순적전최화양화활성,결과표명WO3수식적탄납미관재박최화제비용혼산처리적탄납미관재박최화제대갑순정현출경고적전최화양화활성화경호적은정성.
Nano-WO3-modified carbon nanotube supported Pt nanoparticles (Pt-WO3/CNT) with uniform dimensions were prepared by adsorption and decomposition of ammonium meta-tungstate (AMT) on the surface of CNTs pretreated with HNO3, and H2PtCl6 as the Pt precursor. The samples were characterized by X-ray powder diffraction (XRD) and transmission electron microscopy (TEM). The Pt nanoparticles had a face-centered cubic crystal structure, and were wel dispersed on the external wal s and ports of the WO3/CNTs. The electrocatalytic activity of the samples towards the oxidation of methanol was investigated using cyclic voltammetry and chronoamperometry. The results indicated that the Pt-WO3/CNT catalysts exhibited higher electrocatalytic activity, better anti-poisoning ability, and good stability during methanol oxidation compared with Pt/CNTs used for acid oxidation treatments.