CAJ | 학술논문

采用无氰化学镀金法在聚二甲基硅氧烷(PDMS)印章表面镀金,通过微接触印刷技术将PDMS印章上的Au纳米粒子(AuNPs)分别转移到氧化铟锡(ITO)透明导电膜玻璃,修饰了(3-巯基丙基)三甲氧基硅烷(MPTMS)的ITO基底(MPTMS/ITO)和表面电镀了铜膜的ITO(Cu/ITO)表面上,同时形成有序的结构或者图案.通过场发射扫描电镜(FE-SEM),原子力显微镜(AFM)和显微共聚焦激光拉曼光谱仪等对实验结果进行表征.结果表明,该转移AuNPs的方法对基底表面特性并无特殊要求,是一种简单、快速、无污染、低成本的AuNPs转移技术,而且转移了AuNPs的ITO基底具有表面增强拉曼光谱(SERS)活性,有望在SERS中有所应用.
채용무청화학도금법재취이갑기규양완(PDMS)인장표면도금,통과미접촉인쇄기술장PDMS인장상적Au납미입자(AuNPs)분별전이도양화인석(ITO)투명도전막파리,수식료(3-구기병기)삼갑양기규완(MPTMS)적ITO기저(MPTMS/ITO)화표면전도료동막적ITO(Cu/ITO)표면상,동시형성유서적결구혹자도안.통과장발사소묘전경(FE-SEM),원자력현미경(AFM)화현미공취초격광랍만광보의등대실험결과진행표정.결과표명,해전이AuNPs적방법대기저표면특성병무특수요구,시일충간단、쾌속、무오염、저성본적AuNPs전이기술,이차전이료AuNPs적ITO기저구유표면증강랍만광보(SERS)활성,유망재SERS중유소응용.
A poly(dimethylsiloxane) (PDMS) stamp was electrolessly plated using a cyanide-free solution. Gold nanoparticles (AuNPs) were transferred from the PDMS stamp to indium tin oxide (ITO), (3-mercaptopropyl) trimethoxysilane modified ITO (MPTMS/ITO), and an ITO substrate electrodeposited with a thin copper film (Cu/ITO). AuNPs formed wel-ordered structures which were characterized by field emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM), and Raman spectroscopy. Microcontact printing al owed thin AuNPs films to be directly transferred from PDMS to substrate, so is a simple, fast, cheap and environmental y-friendly technique. AuNPs patterned on the ITO substrate exhibited surface-enhanced Raman spectroscopy (SERS) activity which wil be investigated in subsequent studies.