CAJ | 학술논문

利用水热法在直流磁控溅射制备的掺铝氧化锌(AZO)种子层上制备了不同形貌和光学性能的掺银ZnO纳米棒,并采用XRD、扫描电镜、透射谱、光发射谱和EDS谱详细研究了Ag离子与Zn离子的摩尔百分比(RAg/Zn)及AZO种子层对掺银ZnO纳米棒的结构和光学性质的影响.随着RAg/Zn的增加,掺银ZnO纳米棒的微结构和光学性质的变化与银掺杂诱导的纳米棒的端面尺寸变化有关.平均端面尺寸的变化归结于种子层颗粒大小和颗粒数密度不同导致掺入的Ag离子的相对比例不同.溅射15 min的AZO种子层上生长的ZnO纳米棒由于缺陷增多导致在可见光区的发光峰明显强于溅射10 min的AZO种子层上、相同RAg/Zn条件下生长的ZnO纳米棒. Ag掺杂产生的点缺陷增多导致可见光区PL波包较宽.纯ZnO纳米棒的微结构与种子层厚度导致的结晶度和颗粒大小有关.
이용수열법재직류자공천사제비적참려양화자(AZO)충자층상제비료불동형모화광학성능적참은ZnO납미봉,병채용XRD、소묘전경、투사보、광발사보화EDS보상세연구료Ag리자여Zn리자적마이백분비(RAg/Zn)급AZO충자층대참은ZnO납미봉적결구화광학성질적영향.수착RAg/Zn적증가,참은ZnO납미봉적미결구화광학성질적변화여은참잡유도적납미봉적단면척촌변화유관.평균단면척촌적변화귀결우충자층과립대소화과립수밀도불동도치참입적Ag리자적상대비례불동.천사15 min적AZO충자층상생장적ZnO납미봉유우결함증다도치재가견광구적발광봉명현강우천사10 min적AZO충자층상、상동RAg/Zn조건하생장적ZnO납미봉. Ag참잡산생적점결함증다도치가견광구PL파포교관.순ZnO납미봉적미결구여충자층후도도치적결정도화과립대소유관.
Ag-doped ZnO nanorods with different morphologies and optical properties are synthesized by hydrothermal method on the DC magnetron-sputtered Al-doped ZnO (AZO) seed layers. The influences of the molar ratio of Ag ions to Zn ions (RAg/Zn) and the AZO seed layer on the structural and optical properties of the Ag-doped ZnO nanorods are carefully studied by using X-ray diffractometry, scanning electron microscopy, spectrophotometry, EDS spectrum, etc. The changes in the microstructure and optical property of Ag-doped ZnO nanorods are closely related to the change in the average head-face dimension induced by Ag doping as RAg/Zn increases, owing to the different relative proportions of Ag ions doped in ZnO nanorods resulting from the different particle sizes and densities of the seed layers. The photoluminescence intensity in the visible region for the ZnO nanorods growing on the 15 min-sputtered AZO is stronger than that of the ZnO nanorods growing on the 10 min-sputtered AZO seed layer at the same RAg/Zn, which results from the increased defects in ZnO. More point defects caused by Ag doping are produced as RAg/Zn increases, resulting in the broadening of PL envelope in the visible region. The microstructure of pure ZnO nanorod is related to the seed layer thickness-related degree of crystallinity and particle size.