茶叶科学
茶葉科學
다협과학
2013年
3期
253-260
,共8页
郑德勇%常玉玺%叶乃兴*%杨江帆
鄭德勇%常玉璽%葉迺興*%楊江帆
정덕용%상옥새%협내흥*%양강범
茶籽%气相色谱%高效液相色谱%油脂%维生素 E%角鲨烯%脂肪酸组成
茶籽%氣相色譜%高效液相色譜%油脂%維生素 E%角鯊烯%脂肪痠組成
다자%기상색보%고효액상색보%유지%유생소 E%각사희%지방산조성
tea seeds%GC%HPLC%oil%vitamin E(α-tocopherol)%squalene%fatty acid composition
采用气相色谱法和高效液相色谱法研究了福鼎大白茶、福云6号、黄棪和肉桂4个品种茶籽成熟过程中油脂含量、脂肪酸组成、维生素 E 和角鲨烯含量等主要功能性成分的变化规律.结果表明,随着茶籽成熟程度提高,其中的主要营养物质持续积累,含水率呈下降趋势;茶籽的含油率呈现持续增长的趋势,在成熟前期含油率上升较快,后期趋缓并达到最高值,4个品种茶籽的平均含油率为24.24%;维生素 E 含量均出现“双波峰”增长趋势,并在后期快速增加至最大值,其中福云6号的维生素 E 含量最高达到1060.29μg/g;角鲨烯含量呈现成熟前期增加、后期降低的趋势,其中肉桂的角鲨烯含量为161.42μg/g.在茶籽成熟过程中,棕榈酸的相对质量分数呈现缓慢降低的趋势,而硬脂酸的相对质量分数则呈现缓慢增加的趋势;油酸的相对质量分数总体呈现先增加、再降低、然后持续增加的趋势,福鼎大白茶、福云6号、肉桂和黄棪成熟茶籽的油脂中油酸相对质量分数分别为50.43%、45.98%、52.62%和52.98%;亚油酸的相对质量分数整体呈现成熟前期降低、中期增加、后期再降低的趋势,福云6号、福鼎大白茶、肉桂和黄棪成熟茶籽的油脂中亚油酸相对质量分数分别为31.65%、27.36%、24.66%和24.07%.
採用氣相色譜法和高效液相色譜法研究瞭福鼎大白茶、福雲6號、黃棪和肉桂4箇品種茶籽成熟過程中油脂含量、脂肪痠組成、維生素 E 和角鯊烯含量等主要功能性成分的變化規律.結果錶明,隨著茶籽成熟程度提高,其中的主要營養物質持續積纍,含水率呈下降趨勢;茶籽的含油率呈現持續增長的趨勢,在成熟前期含油率上升較快,後期趨緩併達到最高值,4箇品種茶籽的平均含油率為24.24%;維生素 E 含量均齣現“雙波峰”增長趨勢,併在後期快速增加至最大值,其中福雲6號的維生素 E 含量最高達到1060.29μg/g;角鯊烯含量呈現成熟前期增加、後期降低的趨勢,其中肉桂的角鯊烯含量為161.42μg/g.在茶籽成熟過程中,棕櫚痠的相對質量分數呈現緩慢降低的趨勢,而硬脂痠的相對質量分數則呈現緩慢增加的趨勢;油痠的相對質量分數總體呈現先增加、再降低、然後持續增加的趨勢,福鼎大白茶、福雲6號、肉桂和黃棪成熟茶籽的油脂中油痠相對質量分數分彆為50.43%、45.98%、52.62%和52.98%;亞油痠的相對質量分數整體呈現成熟前期降低、中期增加、後期再降低的趨勢,福雲6號、福鼎大白茶、肉桂和黃棪成熟茶籽的油脂中亞油痠相對質量分數分彆為31.65%、27.36%、24.66%和24.07%.
채용기상색보법화고효액상색보법연구료복정대백다、복운6호、황염화육계4개품충다자성숙과정중유지함량、지방산조성、유생소 E 화각사희함량등주요공능성성분적변화규률.결과표명,수착다자성숙정도제고,기중적주요영양물질지속적루,함수솔정하강추세;다자적함유솔정현지속증장적추세,재성숙전기함유솔상승교쾌,후기추완병체도최고치,4개품충다자적평균함유솔위24.24%;유생소 E 함량균출현“쌍파봉”증장추세,병재후기쾌속증가지최대치,기중복운6호적유생소 E 함량최고체도1060.29μg/g;각사희함량정현성숙전기증가、후기강저적추세,기중육계적각사희함량위161.42μg/g.재다자성숙과정중,종려산적상대질량분수정현완만강저적추세,이경지산적상대질량분수칙정현완만증가적추세;유산적상대질량분수총체정현선증가、재강저、연후지속증가적추세,복정대백다、복운6호、육계화황염성숙다자적유지중유산상대질량분수분별위50.43%、45.98%、52.62%화52.98%;아유산적상대질량분수정체정현성숙전기강저、중기증가、후기재강저적추세,복운6호、복정대백다、육계화황염성숙다자적유지중아유산상대질량분수분별위31.65%、27.36%、24.66%화24.07%.
The variation of important functional composition in the tea seeds, including the oil content, fatty acid composition of tea seeds oil, the content of vitamin E and squalene in tea seeds oil were studied by GC and HPLC on its maturation period. The tea seed samples come from 4 tea germplasms: Fuding dabaicha, Fuyun No.6, Huangdan and Rougui. The results showed that, the nutrients accumulated, the moisture content decreased and the oil content increased on the tea seed maturation process. The oil content increased more rapid at the earlier maturation stage, then slowed down at the later stage and reached a maximum value, the average seed oil content of these 4 germplasm was 24.24%. The vitamin E content in the tea seeds oil increased by the ‘dual wave peak’ pattern, and then increased fast at later stage to a maximum value, the vitamin E content of Fuyun 6 reached 1 060.29 μg/g.The squalene content of tea seeds oil increased at earlier maturation stage, decreased at later stage, the Rougui’s squalene content was 161.42 μg/g. The palmitic acid relative content in tea seeds oil decreased slowly, and the relative content of stearic acid in tea seeds oil increased slowly on the tea seeds maturation. The oleinic acid relative content in tea seeds oil increased firstly, decreased at medium stage, and then increased continually to the end. The oleinic acid relative content in matured tea seeds oil of Fuding dabaicha, Fuyun No. 6, Huangdan and Rougui was 50.43%、45.98%、52.62% and 52.98% respectively. The linoleic acid relative content in tea seeds oil decreased firstly, increased at medium stage, and then decreased continuing to the end. The linoleic acid relative content in matured tea seeds oil of Fuding dabaicha, Fuyun No.6, Huangdan and Rougui was 31.65%、27.36%、24.66% and 24.07%respectively.