化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2013年
6期
1230-1235
,共6页
李桂琴%李刚%陈朝阳%李小森%王屹
李桂琴%李剛%陳朝暘%李小森%王屹
리계금%리강%진조양%리소삼%왕흘
甲烷水合物%多孔介质%降压分解%注热分解%能量效率
甲烷水閤物%多孔介質%降壓分解%註熱分解%能量效率
갑완수합물%다공개질%강압분해%주열분해%능량효솔
methane hydrate%porous sediment%depressurization%thermal stimulation%energy efficiency
冻土区天然气水合物是未来能源的重要补充,然而冻土区天然气水合物的开采研究还处于初级阶段.本文利用一维水合物分解实验装置,在1.24~1.35℃以及2.83~2.89 MPa温度压力条件下,模拟冻土区天然气水合物降压定压分解以及注热水定压分解实验研究,分析降压分解及注热水分解过程中温度、压力、产水以及产气随时间变化特性及能量效率.研究结果表明,分解过程产气可分为自由气释放、水合物分解以及残余气体产出3个阶段,实验过程中温度先降后升,降压分解过程与注热水分解自由气产出阶段基本没有水产出,而在水合物分解阶段,产水速率与注水速率相等.注热分解过程中能量效率先升后降,注热量越大,能量效率越低.
凍土區天然氣水閤物是未來能源的重要補充,然而凍土區天然氣水閤物的開採研究還處于初級階段.本文利用一維水閤物分解實驗裝置,在1.24~1.35℃以及2.83~2.89 MPa溫度壓力條件下,模擬凍土區天然氣水閤物降壓定壓分解以及註熱水定壓分解實驗研究,分析降壓分解及註熱水分解過程中溫度、壓力、產水以及產氣隨時間變化特性及能量效率.研究結果錶明,分解過程產氣可分為自由氣釋放、水閤物分解以及殘餘氣體產齣3箇階段,實驗過程中溫度先降後升,降壓分解過程與註熱水分解自由氣產齣階段基本沒有水產齣,而在水閤物分解階段,產水速率與註水速率相等.註熱分解過程中能量效率先升後降,註熱量越大,能量效率越低.
동토구천연기수합물시미래능원적중요보충,연이동토구천연기수합물적개채연구환처우초급계단.본문이용일유수합물분해실험장치,재1.24~1.35℃이급2.83~2.89 MPa온도압력조건하,모의동토구천연기수합물강압정압분해이급주열수정압분해실험연구,분석강압분해급주열수분해과정중온도、압력、산수이급산기수시간변화특성급능량효솔.연구결과표명,분해과정산기가분위자유기석방、수합물분해이급잔여기체산출3개계단,실험과정중온도선강후승,강압분해과정여주열수분해자유기산출계단기본몰유수산출,이재수합물분해계단,산수속솔여주수속솔상등.주열분해과정중능량효솔선승후강,주열량월대,능량효솔월저.
The gas hydrate in permafrost regions could be an important energy source for future. In this paper,we studied methane hydrate dissociation in a one-dimensional experiment apparatus by depressurization and hot water injection in porous sediments under simulated conditions of 1.24 ℃ to 1.35 ℃ and 2.83 MPa to 2.89 MPa for permafrost regions. The changes of pressure,temperature,gas production,water production and energy efficiency with time were investigated. The results revealed three stages in the gas production process:free gas release,hydrate dissociation and production of remaining gas. In the first stage,there was no water presented in the depressurization or hot water injection process. In the process of the hot water injection,water production rate was equal to water injection rate. The energy efficiency in the hot water injection process increased before it came to a decrease. Lower energy efficiencies associated with higher rates of the water injection.