高等学校化学学报
高等學校化學學報
고등학교화학학보
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES
2014年
12期
2720-2724
,共5页
马彦琼%谭忠阳%李玉杰%王大明%党国栋%陈春海
馬彥瓊%譚忠暘%李玉傑%王大明%黨國棟%陳春海
마언경%담충양%리옥걸%왕대명%당국동%진춘해
聚醚酰亚胺%聚四氟乙烯%石墨%摩擦磨损性能
聚醚酰亞胺%聚四氟乙烯%石墨%摩抆磨損性能
취미선아알%취사불을희%석묵%마찰마손성능
Polyetherimide%Polytetrafluoroethylene%Graphite%Tribological performance
将聚四氟乙烯( PTFE)和石墨两类减摩耐磨填料填充到聚醚酰亚胺( PEI)中,表征其摩擦性能,利用扫描电子显微镜分析了磨损表面的显微结构,并分析了磨损机制.研究结果表明, PTFE和石墨的填充明显改善了PEI的摩擦磨损性,摩擦系数降低到0.3以下(纯PEI的摩擦系数为0.41),磨损率降低了3个数量级.在PTFE体系中, PTFE质量分数为10%时, PEI基共混材料的摩擦系数最低为0.23;而在质量分数为15%的石墨体系中, PEI基共混材料摩擦系数最低为0.27.磨损率随着填料含量的增加而逐渐下降,在填料质量分数为20%之后,摩损率下降平缓.因此PTFE和石墨的填充对PEI的摩擦学性能起到了很好的改善作用,而且PTFE比石墨的改善效果更优益.共混物的机械性能测试结果表明,在填料质量分数为5%~15%时,共混物具有良好的机械性能.
將聚四氟乙烯( PTFE)和石墨兩類減摩耐磨填料填充到聚醚酰亞胺( PEI)中,錶徵其摩抆性能,利用掃描電子顯微鏡分析瞭磨損錶麵的顯微結構,併分析瞭磨損機製.研究結果錶明, PTFE和石墨的填充明顯改善瞭PEI的摩抆磨損性,摩抆繫數降低到0.3以下(純PEI的摩抆繫數為0.41),磨損率降低瞭3箇數量級.在PTFE體繫中, PTFE質量分數為10%時, PEI基共混材料的摩抆繫數最低為0.23;而在質量分數為15%的石墨體繫中, PEI基共混材料摩抆繫數最低為0.27.磨損率隨著填料含量的增加而逐漸下降,在填料質量分數為20%之後,摩損率下降平緩.因此PTFE和石墨的填充對PEI的摩抆學性能起到瞭很好的改善作用,而且PTFE比石墨的改善效果更優益.共混物的機械性能測試結果錶明,在填料質量分數為5%~15%時,共混物具有良好的機械性能.
장취사불을희( PTFE)화석묵량류감마내마전료전충도취미선아알( PEI)중,표정기마찰성능,이용소묘전자현미경분석료마손표면적현미결구,병분석료마손궤제.연구결과표명, PTFE화석묵적전충명현개선료PEI적마찰마손성,마찰계수강저도0.3이하(순PEI적마찰계수위0.41),마손솔강저료3개수량급.재PTFE체계중, PTFE질량분수위10%시, PEI기공혼재료적마찰계수최저위0.23;이재질량분수위15%적석묵체계중, PEI기공혼재료마찰계수최저위0.27.마손솔수착전료함량적증가이축점하강,재전료질량분수위20%지후,마손솔하강평완.인차PTFE화석묵적전충대PEI적마찰학성능기도료흔호적개선작용,이차PTFE비석묵적개선효과경우익.공혼물적궤계성능측시결과표명,재전료질량분수위5%~15%시,공혼물구유량호적궤계성능.
The tribological performances of polyetherimide( PEI) composite materials filled with polytetraflu-oroethylene( PTFE) and graphite were evaluated on UMT-2 friction and wear tester, respectively. The micro-structures of worn surfaces, cross-sections of the PEI composite were examined with scanning electron micro-scope( SEM) , and wear mechanism was analyzed. The result showed that PEI composite filled with PTFE and graphite were improved significantly on friction and wear properties. The friction coefficient is reduced to below 0. 3(the friction coefficient of pure PEI is 0. 41), the wear rate is reduced by 3 orders of magnitude. When filled with 10%PTFE in composites PTFE system, the friction coefficient of the composites is lowest, and the friction coefficient of the graphite counterpart is lowest in 15% graphite content. The lowest friction coefficient is 0. 23 and 0. 27. For the wear rate, PEI composite materials filled with PTFE and graphite are both de-creased with the content increasing respectively. Consequently, compared with the PEI composite materials filled with graphite, the PEI composite materials filled with PTFE has more excellent tribological performance and mechanical behavior. The mechanical behavior of two kinds of the PEI composites was also measured, such as tensile strength, bending strength, impact strength and Rockwell hardness. The results show that, when the mass fraction of 5%—15%, which is the best tribological performance improvement in addition, comprehensive mechanical properties of blends of materials is still good.