工程塑料应用
工程塑料應用
공정소료응용
ENGINEERING PLASTICS APPLICATION
2014年
11期
93-96
,共4页
刘玉坤%牛帅%牛景新%刘文涛%何素芹%朱诚身
劉玉坤%牛帥%牛景新%劉文濤%何素芹%硃誠身
류옥곤%우수%우경신%류문도%하소근%주성신
尼龙1010%硅灰石%热膨胀%热变形%热分解%熔融与结晶
尼龍1010%硅灰石%熱膨脹%熱變形%熱分解%鎔融與結晶
니룡1010%규회석%열팽창%열변형%열분해%용융여결정
nylon1010%wollastonite%thermal expansion%heat deflection%thermal decomposition%melting and crystallization
通过熔融共混法制备了尼龙1010/硅灰石复合材料,研究了复合材料的热膨胀性能、热变形温度、热分解过程和熔融及结晶行为。结果表明,与纯尼龙1010相比,尼龙1010/硅灰石复合材料的热膨胀系数及其温度依赖性大幅下降。当硅灰石质量分数为70%时,复合材料的热膨胀系数及其随温度的增加率分别只有纯尼龙1010的29%和15%。复合材料的热变形温度随硅灰石含量的增加大幅升高,当硅灰石质量分数为70%时,热变形温度由纯尼龙1010的63℃升高到178℃;复合材料的起始热分解温度和最大热分解速率时的温度均明显升高。硅灰石的加入显著提高了尼龙1010的热稳定性。尼龙1010的熔融温度和结晶温度不受硅灰石的影响,复合材料熔体仍具有良好的加工成型性。
通過鎔融共混法製備瞭尼龍1010/硅灰石複閤材料,研究瞭複閤材料的熱膨脹性能、熱變形溫度、熱分解過程和鎔融及結晶行為。結果錶明,與純尼龍1010相比,尼龍1010/硅灰石複閤材料的熱膨脹繫數及其溫度依賴性大幅下降。噹硅灰石質量分數為70%時,複閤材料的熱膨脹繫數及其隨溫度的增加率分彆隻有純尼龍1010的29%和15%。複閤材料的熱變形溫度隨硅灰石含量的增加大幅升高,噹硅灰石質量分數為70%時,熱變形溫度由純尼龍1010的63℃升高到178℃;複閤材料的起始熱分解溫度和最大熱分解速率時的溫度均明顯升高。硅灰石的加入顯著提高瞭尼龍1010的熱穩定性。尼龍1010的鎔融溫度和結晶溫度不受硅灰石的影響,複閤材料鎔體仍具有良好的加工成型性。
통과용융공혼법제비료니룡1010/규회석복합재료,연구료복합재료적열팽창성능、열변형온도、열분해과정화용융급결정행위。결과표명,여순니룡1010상비,니룡1010/규회석복합재료적열팽창계수급기온도의뢰성대폭하강。당규회석질량분수위70%시,복합재료적열팽창계수급기수온도적증가솔분별지유순니룡1010적29%화15%。복합재료적열변형온도수규회석함량적증가대폭승고,당규회석질량분수위70%시,열변형온도유순니룡1010적63℃승고도178℃;복합재료적기시열분해온도화최대열분해속솔시적온도균명현승고。규회석적가입현저제고료니룡1010적열은정성。니룡1010적용융온도화결정온도불수규회석적영향,복합재료용체잉구유량호적가공성형성。
Nylon1010/wollastonite composites were prepared by melt blending. The thermal expansion coefficient,heat deflection temperature,thermal decomposition,melting and crystallization behaviors were studied. The results show that the thermal expansion coefficient and its dependence on temperature of nylon1010/wollastonite composites decrease dramatically with the increasing of the wollastonite content. The thermal expansion coefficient of nylon1010 with wollastonite mass fraction of 70%and its increment rate are 29%and 15%of the pure nylon1010 respectively. The heat deflection temperature of the composites gradually increases with wollastonite content increasing,when the mass fraction of wollastonite is 70%,the heat deflection temperature is 178℃from 63℃of the pure nylon1010. The initial decomposition temperature and the temperature of the maximum thermal decom-position rate of the composites raise obviously. So,with the addition of wollastonite,the thermostability of nylon1010 got much better. The addition of wollastonite don’t effect almost the melting temperature and crystallization temperature of nylon1010,the composites have good extrusion and injection molding performance.