CAJ | 학술논문

2,2’-二甲基-4,4’-亚甲基双(环己胺)(DMDC)%癸二酸%11-氨基十一酸%癸二酰2,2’-二甲基-4,4’-亚甲基双(环己胺)-11-氨基十一酸共聚酰胺(PADMDC10/11)%合成 2,2’-二甲基-4,4’-亞甲基雙(環己胺)(DMDC)%癸二痠%11-氨基十一痠%癸二酰2,2’-二甲基-4,4’-亞甲基雙(環己胺)-11-氨基十一痠共聚酰胺(PADMDC10/11)%閤成
2,2’-이갑기-4,4’-아갑기쌍(배기알)(DMDC)%계이산%11-안기십일산%계이선2,2’-이갑기-4,4’-아갑기쌍(배기알)-11-안기십일산공취선알(PADMDC10/11)%합성
2,2’-dimethyl-4,4’-methylenebis(cyclohexylamine)(DMDC)%sebacic acid%11-aminoundecanoic acid%2,2’-dimethyl-4,4’-methylenebis(cyclohexyl) sebacamide-11-aminoundecanoic acid copolyamide(PADMDC10/11)%synthesis

以2，2’-二甲基-4，4’-亚甲基双（环己胺）(DMDC)、癸二酸和11-氨基十一酸为单体，采用熔融缩聚的方法合成了透明癸二酰[2，2’-二甲基-4，4’-亚甲基双（环己胺）]-11-氨基十一酸共聚酰胺(PADMDC10／11)。利用特性黏度、红外光谱、透光率和差示扫描量热法测试对产物进行表征分析。结果表明，合成的PADMDC10／11是非晶态的。PADMDC10盐的物质的量分数由60%增加到100%时，透明PADMDC10／11的特性黏度都在1.0 dL／g左右，玻璃化转变温度由126℃上升到165℃，透光率由86.2%上升到91.4%，表明PADMDC10／11具有良好的耐热性能和透明性能。
이2，2’-이갑기-4，4’-아갑기쌍（배기알）(DMDC)、계이산화11-안기십일산위단체，채용용융축취적방법합성료투명계이선[2，2’-이갑기-4，4’-아갑기쌍（배기알）]-11-안기십일산공취선알(PADMDC10／11)。이용특성점도、홍외광보、투광솔화차시소묘량열법측시대산물진행표정분석。결과표명，합성적PADMDC10／11시비정태적。PADMDC10염적물질적량분수유60%증가도100%시，투명PADMDC10／11적특성점도도재1.0 dL／g좌우，파리화전변온도유126℃상승도165℃，투광솔유86.2%상승도91.4%，표명PADMDC10／11구유량호적내열성능화투명성능。
Taking 2,2’-dimethyl-4,4’-methylenebis(cyclohexylamine)(DMDC),sebacic acid and 11-aminoundecanoic acid as the monomers,transparent 2,2’-dimethyl-4,4’-methylenebis(cyclohexyl) sebacamide-11-aminoundecanoic acid copolyamide(PADMDC10/11) was synthesized through the process of melt polycondensation. PADMDC10/11 was characterized and analyzed by means of intrinsic viscosity,infrared spectrum,light transmittance and differential scanning calorimetry. The results show that PADMDC10/11 is amorphous. With the amount of substance of PADMDC10 salt fraction increase from 60%to 100%,the intrinsic viscosity of transparent PADMDC10/11 is around 1.0 dL/g,the glass transition temperature increases from 126℃to 165℃,the transmittance increases from 86.2%to 91.4%,which showes that the PADMDC10/11 has well heat resistance properties and transparency properties.