工程塑料应用
工程塑料應用
공정소료응용
ENGINEERING PLASTICS APPLICATION
2014年
11期
6-10
,共5页
张博%王汝敏%江浩%强雪原%刘翔
張博%王汝敏%江浩%彊雪原%劉翔
장박%왕여민%강호%강설원%류상
环氧树脂%超支化聚合物%增韧%改性
環氧樹脂%超支化聚閤物%增韌%改性
배양수지%초지화취합물%증인%개성
epoxy resin%hyperbranched polymer%toughening%modification
通过有核一步法,合成了端羧基超支化聚酯(CHP),然后与环氧氯丙烷经环氧化反应制备了端环氧基超支化聚酯(EHP),并制备了EHP改性环氧树脂(EP)体系。利用傅立叶变换红外光谱法、核磁共振氢谱法、凝胶渗透色谱法、差示扫描量热法、热变形温度分析、热失重分析、扫描电子显微镜等对EHP结构、改性EP体系固化工艺、力学性能、热性能等进行了研究。结果表明,合成了预期结构的EHP,数均分子量为1908 g/mol,黏度为1522.5 mPa · s;当EHP含量为15 g时,改性EP体系的性能最佳,其冲击强度和弯曲强度分别为50.4 kJ/m2,201.0 MPa,较改性前分别提高了213%,37%;热变形温度为147.5℃,热失重10%时的温度为360℃,较改性前分别下降了9%,7.7%。
通過有覈一步法,閤成瞭耑羧基超支化聚酯(CHP),然後與環氧氯丙烷經環氧化反應製備瞭耑環氧基超支化聚酯(EHP),併製備瞭EHP改性環氧樹脂(EP)體繫。利用傅立葉變換紅外光譜法、覈磁共振氫譜法、凝膠滲透色譜法、差示掃描量熱法、熱變形溫度分析、熱失重分析、掃描電子顯微鏡等對EHP結構、改性EP體繫固化工藝、力學性能、熱性能等進行瞭研究。結果錶明,閤成瞭預期結構的EHP,數均分子量為1908 g/mol,黏度為1522.5 mPa · s;噹EHP含量為15 g時,改性EP體繫的性能最佳,其遲擊彊度和彎麯彊度分彆為50.4 kJ/m2,201.0 MPa,較改性前分彆提高瞭213%,37%;熱變形溫度為147.5℃,熱失重10%時的溫度為360℃,較改性前分彆下降瞭9%,7.7%。
통과유핵일보법,합성료단최기초지화취지(CHP),연후여배양록병완경배양화반응제비료단배양기초지화취지(EHP),병제비료EHP개성배양수지(EP)체계。이용부립협변환홍외광보법、핵자공진경보법、응효삼투색보법、차시소묘량열법、열변형온도분석、열실중분석、소묘전자현미경등대EHP결구、개성EP체계고화공예、역학성능、열성능등진행료연구。결과표명,합성료예기결구적EHP,수균분자량위1908 g/mol,점도위1522.5 mPa · s;당EHP함량위15 g시,개성EP체계적성능최가,기충격강도화만곡강도분별위50.4 kJ/m2,201.0 MPa,교개성전분별제고료213%,37%;열변형온도위147.5℃,열실중10%시적온도위360℃,교개성전분별하강료9%,7.7%。
Epoxy-end hyperbranched polyester(EHP) was successfully synthesized via the epoxidized reaction between epichlorohydrin and carboxy-end hyperbranched polyester(CHP) obtained by one-step process with core monomers. Furthermore, EHP modified epoxy resin(EP) system was prepared. The structure of EHP was analyzed by fourier transform infrared spectroscopy, nuclear magnetic resonance hydrogen spectroscopy and gel permeation chromatography. The curing process,mechanical properties and thermal properties of the modified EP system was studied by differential scanning calorimetry,heat distortion temperature analysis,thermogravimetric analysis and scanning electron microscope. The results reveal that the expected structure EHP is successfully synthesized with the number average molecular weight of 1 908 g/mol and viscosity of 1 522.5 mPa · s. When the EHP content is 15 g,the modified EP system shows the best properties. Compared with unmodified EP system,the impact strength is 50.4 kJ/m2 and increased by 213%,the bending strength is 201.0 MPa and increased by 37%,but the heat distortion temperature is 147.5℃and reduced by 9%,the temperature of thermal weight loss 10%is 360℃and reduced by 7.7%.