CAJ | 학술논문

利用纯度99％的脱氢枞酸为原料经酰氯化、酰胺化和氧化三步反应合成了一种含松香基三元菲环结构的新型氧化酰胺－N ，N－二乙基脱氢枞基氧化酰胺。采用红外光谱（FT－IR）、核磁（1 H NMR）对其结构进行表征，并通过 L4（4）正交试验，对双氧水氧化法合成氧化叔胺的工艺条件进行了优化研究，制备反应的最佳工艺条件：反应温度80℃，反应时间12h ，双氧水与叔胺的物质的量比为1．5：1，催化剂用量1．5％。在优化的工艺条件下重复试验，氧化叔胺的转化率产率均大于72％。产物的临界胶束浓度（CMC）为0．005g · L－1，表面张力为36．75mN · m－1。
이용순도99％적탈경종산위원료경선록화、선알화화양화삼보반응합성료일충함송향기삼원비배결구적신형양화선알－N ，N－이을기탈경종기양화선알。채용홍외광보（FT－IR）、핵자（1 H NMR）대기결구진행표정，병통과 L4（4）정교시험，대쌍양수양화법합성양화숙알적공예조건진행료우화연구，제비반응적최가공예조건：반응온도80℃，반응시간12h ，쌍양수여숙알적물질적량비위1．5：1，최화제용량1．5％。재우화적공예조건하중복시험，양화숙알적전화솔산솔균대우72％。산물적림계효속농도（CMC）위0．005g · L－1，표면장력위36．75mN · m－1。
After three-step reaction ,chloride ,amidation ,and oxidation ,dehydroabietic acid of 99%purity used as raw material was synthesized intoa new oxidative amide ,N ,N- diethyl Dehydroabietyl Oxida‐tion amine containing rosin-based ternary phenanthrene ring structure .Using infrared spectroscopy (FTIR) , nuclear magnetic resonance (1 H NMR) to characterize its structure and through L4 (4) orthogonal test ,the ar‐ticle researched how to optimize process conditions on the synthesis of tertiary amine oxide through hydrogen per‐oxide oxidation .the most optimized reaction conditions are:The reaction temperature is 80 ℃ ,reaction time is 12h ,molar ratio of hydrogen peroxide and tertiary amine is 1 .5:1 ,and the amount of catalyst is 1 .5% .Un‐der optimized conditions ,repeat the experiment ,the conversion rate of the tertiary amine oxide and the produc‐tion rate is all greater than 72% .The critical micelle concentration (CMC) of the product is 0 .005g o L-1 ,and the surface tension is 36 .75mN o m-1 .