应用化工
應用化工
응용화공
APPLIED CHEMICAL INDUSTRY
2014年
11期
2033-2036,2041
,共5页
李宇航%奚晓翔%李东风%侯瑞斌
李宇航%奚曉翔%李東風%侯瑞斌
리우항%해효상%리동풍%후서빈
四硫富瓦烯%超分子化学%自主装%凝胶%酰胺%氢键
四硫富瓦烯%超分子化學%自主裝%凝膠%酰胺%氫鍵
사류부와희%초분자화학%자주장%응효%선알%경건
tetrathiafulvalene%supramolecular chemistry%self-assemble%gel%amide%hydrogen-bond
合成了含有脂肪酰胺基的四硫富瓦烯凝胶因子,测试其在不同有机溶剂中形成凝胶的能力。结果表明,凝胶因子能够与多种有机溶剂形成稳定的凝胶,最低成胶浓度可达0.1%。FTIR表明,分子间的氢键作用是形成凝胶的主要驱动力。同时,利用循环伏安、扫描电镜和其它方法研究了凝胶的性能。
閤成瞭含有脂肪酰胺基的四硫富瓦烯凝膠因子,測試其在不同有機溶劑中形成凝膠的能力。結果錶明,凝膠因子能夠與多種有機溶劑形成穩定的凝膠,最低成膠濃度可達0.1%。FTIR錶明,分子間的氫鍵作用是形成凝膠的主要驅動力。同時,利用循環伏安、掃描電鏡和其它方法研究瞭凝膠的性能。
합성료함유지방선알기적사류부와희응효인자,측시기재불동유궤용제중형성응효적능력。결과표명,응효인자능구여다충유궤용제형성은정적응효,최저성효농도가체0.1%。FTIR표명,분자간적경건작용시형성응효적주요구동력。동시,이용순배복안、소묘전경화기타방법연구료응효적성능。
The synthesis of tetrathiafulvalene gelator containing fatty amide group and the ability of the synthesized compouds forming organogel in different organic solvents is investigated. The ability of target compound forming organogel was studied. The result showed that the compoud can form organogel in a va-riety of solvents,and the minimum concentration of gelation is 0. 1%. The FTIR showed that the hydrogen bonds are the main driving force of gel formation. At the same time,study the properties of the gel by cy-clic voltammograms,scanning electron microscopy and other methods.