CAJ | 학술논문

针对邻氰基氯苄和苯使用存在的污染问题，探讨以邻氰基甲苯为原料，经侧链氯化得到邻氰基氯苄，然后直接与过量亚磷酸三乙酯进行酯化反应生成邻氰基苄基亚磷酸二乙酯的绿色合成工艺。研究表明，以白炽灯为催化光源，氯化反应温度140℃，氯化深度1.0，酯化温度155℃，酯化反应时间4 h为最佳工艺条件；严格控制氯化深度在1.0以下是保证产品质量的关键；将光氯化和酯化过程联用，减少环境污染。
침대린청기록변화분사용존재적오염문제，탐토이린청기갑분위원료，경측련록화득도린청기록변，연후직접여과량아린산삼을지진행지화반응생성린청기변기아린산이을지적록색합성공예。연구표명，이백치등위최화광원，록화반응온도140℃，록화심도1.0，지화온도155℃，지화반응시간4 h위최가공예조건；엄격공제록화심도재1.0이하시보증산품질량적관건；장광록화화지화과정련용，감소배경오염。
Aiming at pollution from o-cyanobenzyl chloride and benzene,a green synthesis process was provided by using o-cyanotoluene as starting molecular,after photochlorination,o-cyanobenzyl chloride di-rectly reacted with a slight excess of triethyl phosphate by esterification reaction without adding other or-ganic solvents. The results show that the optimal technological condition is chlorination at 140 ℃,1. 0 of chlorination degree,using incandescent light bulb,esterification at 155 ℃ for 4 h. The critical factor is controlling chlorination degree under 1. 0,combination of photochlorination and esterification,in order to reduce pollution to enviroment.