应用化工
應用化工
응용화공
APPLIED CHEMICAL INDUSTRY
2014年
11期
1973-1976
,共4页
席夫碱%缓蚀剂%失重%动电位极化
席伕堿%緩蝕劑%失重%動電位極化
석부감%완식제%실중%동전위겁화
Schiff base%inhibitor%weight loss%potentiodynamic polarization
合成了一种新型缓蚀剂2-羟基-4-甲氧基苯甲醛缩氨基硫脲( HMBT),采用静态失重和动电位极化曲线法探讨了其在盐酸介质中对 Q235碳钢缓蚀性能。结果表明,随着缓蚀剂浓度提高,碳钢的腐蚀速率下降,因此HMBT可以作为一种良好的缓蚀剂。HMBT在碳钢表面的吸附遵循Langmuir吸附等温式,HMBT分子在碳钢表面的吸附自由能表明既包括物理吸附也包括化学吸附。动电位极化的测量结果表明HMBT是一种混合型的缓蚀剂。
閤成瞭一種新型緩蝕劑2-羥基-4-甲氧基苯甲醛縮氨基硫脲( HMBT),採用靜態失重和動電位極化麯線法探討瞭其在鹽痠介質中對 Q235碳鋼緩蝕性能。結果錶明,隨著緩蝕劑濃度提高,碳鋼的腐蝕速率下降,因此HMBT可以作為一種良好的緩蝕劑。HMBT在碳鋼錶麵的吸附遵循Langmuir吸附等溫式,HMBT分子在碳鋼錶麵的吸附自由能錶明既包括物理吸附也包括化學吸附。動電位極化的測量結果錶明HMBT是一種混閤型的緩蝕劑。
합성료일충신형완식제2-간기-4-갑양기분갑철축안기류뇨( HMBT),채용정태실중화동전위겁화곡선법탐토료기재염산개질중대 Q235탄강완식성능。결과표명,수착완식제농도제고,탄강적부식속솔하강,인차HMBT가이작위일충량호적완식제。HMBT재탄강표면적흡부준순Langmuir흡부등온식,HMBT분자재탄강표면적흡부자유능표명기포괄물리흡부야포괄화학흡부。동전위겁화적측량결과표명HMBT시일충혼합형적완식제。
A new corrosion inhibitor 2-hydroxy-4-methoxy benzaldehyde thiosemicarbazone( HMBT )was synthesized. The corrosion inhibition effect of HMBT on mild steel was evaluated in 1 mol/L HCl by means of weight loss and potentiodynamic polarization. The results show that the corrosion rate of mild steel decreases with the increasing concentration of inhibitor. Thus,HMBT can serve as a good inhibitor. The adsorption of HMBT on Q235 steel surface obeys Langmuir adsorption isotherm,including both physi-cal and chemical adsorption. The results of potentiodynamic polarization measurements indicate that HMBT is a mixed-type inhibitor.