CAJ | 학술논문

总结了周期表元素与Pd的相互作用，按富Pd合金的相图特征，采用经典合金化理论和米德玛键参数分析了固溶度的规律性。建立了周期表元素在 Pd 中的溶解度方程：lnCmax =4.6052–k(|?nws1/3|–nR)，溶质在Pd溶剂中的极限固溶度(lnCmax)是Pd溶剂与溶质之间的电子密度差|?nws1/3|的减函数。当Pd溶剂与溶质之间的电子密度差|?nws1/3|相同时，简单金属溶质在Pd中的固溶度大于过渡金属溶质，简单金属和过渡金属溶质在 Pd 溶剂中具有不同的固溶机制。分析了惣各贵金属元素作为溶剂对周期表元素的溶解能力指数与溶质元素电子密度nws1/3的关系，Pd作为溶剂对周期表元素具有最大溶解能力。
총결료주기표원소여Pd적상호작용，안부Pd합금적상도특정，채용경전합금화이론화미덕마건삼수분석료고용도적규률성。건립료주기표원소재 Pd 중적용해도방정：lnCmax =4.6052–k(|?nws1/3|–nR)，용질재Pd용제중적겁한고용도(lnCmax)시Pd용제여용질지간적전자밀도차|?nws1/3|적감함수。당Pd용제여용질지간적전자밀도차|?nws1/3|상동시，간단금속용질재Pd중적고용도대우과도금속용질，간단금속화과도금속용질재 Pd 용제중구유불동적고용궤제。분석료총각귀금속원소작위용제대주기표원소적용해능력지수여용질원소전자밀도nws1/3적관계，Pd작위용제대주기표원소구유최대용해능력。
Some regularities of interactions of palladium with periodic table elements were summarized, and the solid solubilities of periodic table elements in palladium were analyzed by the classical solid solubility theory and Miedema’s bond parameters. A solubility equation, lnCmax=4.6052–k (|?nws1/3|–nR), was established, the limit solid solubility (lnCmax), of solutes in palladium increases with the electron density difference,|?nws1/3|, between them. The solid solubilities of the simple metal solutes in palladium are larger than those of transition metal solutes with same?nws1/3 based on different solubility mechanisms. The relationship of solvability ability indexes of precious metals as solvents with their electron density nws1/3 were analyzed by their electron density parameters nws1/3, and the palladium solvent has the largest solubility ability index for periodic table elements as solutes.