功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2014年
24期
24041-24045
,共5页
吴唯%蔺兴清%钟宇华%姜晨晨%张禄冲
吳唯%藺興清%鐘宇華%薑晨晨%張祿遲
오유%린흥청%종우화%강신신%장록충
尼龙 6%聚乙烯-辛烯弹性体%多壁碳纳米管%增韧%增强
尼龍 6%聚乙烯-辛烯彈性體%多壁碳納米管%增韌%增彊
니룡 6%취을희-신희탄성체%다벽탄납미관%증인%증강
PA6%POE%MWNTs%tougheness%enhancement
研究了聚乙烯-辛烯弹性体接枝马来酸(POE-g-MAH)和多壁碳纳米管(MWNTs)对尼龙6(PA6)的增韧增强作用。结果表明,对 MWNTs 酸化处理可在表面成功接枝上羧酸基团,并与 PA6上的酰胺基团化学键合,提高MWNTs在PA6基体中的分散性,增加界面结合力,更好地承受载荷,可对 PA6/POE-g-AMAH 共混增韧材料产生良好的增强效果。 PA6/POE-g-AMAH/a-MWNTs(质量比为70/30/1)三元共混材料在保持纯 PA6拉伸强度和弯曲强度的同时,冲击强度比纯 PA6提高了6倍,是一种理想的高强高韧工程塑料。
研究瞭聚乙烯-辛烯彈性體接枝馬來痠(POE-g-MAH)和多壁碳納米管(MWNTs)對尼龍6(PA6)的增韌增彊作用。結果錶明,對 MWNTs 痠化處理可在錶麵成功接枝上羧痠基糰,併與 PA6上的酰胺基糰化學鍵閤,提高MWNTs在PA6基體中的分散性,增加界麵結閤力,更好地承受載荷,可對 PA6/POE-g-AMAH 共混增韌材料產生良好的增彊效果。 PA6/POE-g-AMAH/a-MWNTs(質量比為70/30/1)三元共混材料在保持純 PA6拉伸彊度和彎麯彊度的同時,遲擊彊度比純 PA6提高瞭6倍,是一種理想的高彊高韌工程塑料。
연구료취을희-신희탄성체접지마래산(POE-g-MAH)화다벽탄납미관(MWNTs)대니룡6(PA6)적증인증강작용。결과표명,대 MWNTs 산화처리가재표면성공접지상최산기단,병여 PA6상적선알기단화학건합,제고MWNTs재PA6기체중적분산성,증가계면결합력,경호지승수재하,가대 PA6/POE-g-AMAH 공혼증인재료산생량호적증강효과。 PA6/POE-g-AMAH/a-MWNTs(질량비위70/30/1)삼원공혼재료재보지순 PA6랍신강도화만곡강도적동시,충격강도비순 PA6제고료6배,시일충이상적고강고인공정소료。
The effect of nylon 6 (PA6 )toughened and enhanced by polyethylene-octene elastomer with maleic acid (POE-g-MAH)and multi-walled carbon nanotubes (MWNTs)were studied in this paper.The results indi-cated that the carboxylic groups that can bond with the amide groups of PA6 were successfully grafted on the surface of MWNTs through acidification,which can improve the dispersion of MWNTs in PA6 and increase the interfacial bonding strength so that the composites can endure more loads and which can also bring about the better enhancement effect for PA6/POE-g-MAH toughening Materials.The notch impact strength of PA6/POE-g-MAH/a-MWNTs(mass ratio of 69/30/1)that was an ideal high strength and high toughness engineering plas-tics was 6 times as that of PA6,while PA6/POE-g-MAH/a-MWNTs and PA6 had the same tensile and bending strength.