功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2015年
1期
1055-1060
,共6页
冉奋%刘影%王翎任%刘卯成%张宣宣%范会利%宋海明%申魁文%孔令斌%康龙
冉奮%劉影%王翎任%劉卯成%張宣宣%範會利%宋海明%申魁文%孔令斌%康龍
염강%류영%왕령임%류묘성%장선선%범회리%송해명%신괴문%공령빈%강룡
超级电容器%Mn O 2%反应温度%水热法%电极材料
超級電容器%Mn O 2%反應溫度%水熱法%電極材料
초급전용기%Mn O 2%반응온도%수열법%전겁재료
supercapacitor%manganese oxide%reaction temperature%hydrothermal method%electrode material
采用简单的水热法制备了具有均一八面分子筛(OMS-2)结构的隐甲锰矿型二氧化锰(MnO2);通过水热反应温度控制 Mn O 2的微纳结构,研究反应温度对其超级电容器性能的影响。采用扫描电子显微镜(SEM)、X 射线衍射(XRD)和透射电子显微镜(TEM)表征材料的结构特点;采用循环伏安和恒流充放电测试其电化学电容性能。结果表明,制备的Mn O 2具有纳米刺或纳米棒形成放射状结构,随着反应温度的增加,Mn O 2晶体逐渐生长完全,从针状纳米刺转变成四方形纳米棒;制备的 Mn O 2具有双电层电容和法拉第准电容的双重特征,在5 mA/cm2的电流密度下,最高比电容达到了603 F/g;在100~180℃的范围内,比容量随着反应温度的升高而逐渐降低。
採用簡單的水熱法製備瞭具有均一八麵分子篩(OMS-2)結構的隱甲錳礦型二氧化錳(MnO2);通過水熱反應溫度控製 Mn O 2的微納結構,研究反應溫度對其超級電容器性能的影響。採用掃描電子顯微鏡(SEM)、X 射線衍射(XRD)和透射電子顯微鏡(TEM)錶徵材料的結構特點;採用循環伏安和恆流充放電測試其電化學電容性能。結果錶明,製備的Mn O 2具有納米刺或納米棒形成放射狀結構,隨著反應溫度的增加,Mn O 2晶體逐漸生長完全,從針狀納米刺轉變成四方形納米棒;製備的 Mn O 2具有雙電層電容和法拉第準電容的雙重特徵,在5 mA/cm2的電流密度下,最高比電容達到瞭603 F/g;在100~180℃的範圍內,比容量隨著反應溫度的升高而逐漸降低。
채용간단적수열법제비료구유균일팔면분자사(OMS-2)결구적은갑맹광형이양화맹(MnO2);통과수열반응온도공제 Mn O 2적미납결구,연구반응온도대기초급전용기성능적영향。채용소묘전자현미경(SEM)、X 사선연사(XRD)화투사전자현미경(TEM)표정재료적결구특점;채용순배복안화항류충방전측시기전화학전용성능。결과표명,제비적Mn O 2구유납미자혹납미봉형성방사상결구,수착반응온도적증가,Mn O 2정체축점생장완전,종침상납미자전변성사방형납미봉;제비적 Mn O 2구유쌍전층전용화법랍제준전용적쌍중특정,재5 mA/cm2적전류밀도하,최고비전용체도료603 F/g;재100~180℃적범위내,비용량수착반응온도적승고이축점강저。
In this article,the uniform cryptomelane-type manganese oxide with an octahedral molecular sieves structure was prepared under mild hydrothermal condition;the effects of hydrothermal temperature on the mi-cro-nanostructure and supercapacitance properties of manganese dioxide were studied in detail.The structures were characterized by SEM,XRD and TEM;and the supercapacitive behaviors were investigated with cyclic voltammetry,galvanostatic charge and discharge tests.The experiment results suggested that:the prepared nanoparticles can be self-organized into dendritic nanostructures,and the nanocluster arrays are composed of nanoneedles or tetragonal prism nanorods;with the increase of reaction temprature,the crystal morphology of manganese oxide was gradually improving,and was trasformed from nanoneedles to tetragonal prism nanorods;the capacitance of MnO2 electrode was a combined contribution of electrical double-layer capacitance and pseud-ocapacitance,and the best specific capacitance value of MnO2 electrode was 603 F/g corresponding to the charge/discharge current density of 5 mA/cm2;with the increase of reaction temperature ranging from 100-180℃,the specific capacitance of manganese oxide gradually decline.