CAJ | 학술논문

采用煤基活性炭为载体，通过20%稀HNO3氧化处理，先后接枝γ-胺丙基-三-乙氧基硅烷、偏苯三酸酐，络合反应，成功制备了含双羧基双齿配体配合铁铬离子催化剂，其结构通过FT-IR、SEM、XRD等手段得到确证。经初步实验评估发现，该催化剂氧化甲苯合成苯甲醛的收率最高可达16.9%，选择性达72.5%。
채용매기활성탄위재체，통과20%희HNO3양화처리，선후접지γ-알병기-삼-을양기규완、편분삼산항，락합반응，성공제비료함쌍최기쌍치배체배합철락리자최화제，기결구통과FT-IR、SEM、XRD등수단득도학증。경초보실험평고발현，해최화제양화갑분합성분갑철적수솔최고가체16.9%，선택성체72.5%。
Coal based activated carbon activated carbon was used as carrier to covalently immobilize Cr3+complexes after 20%HNO3 oxidation treatment. New types of double carboxyl-containing bidentate ligands were subsequently synthesized by grafting the oxidized coal based activated carbon with NH2(CH2)3Si(OC2H5), trimellitic anhydride and complexation reaction.The samples were characterized by FT-IR, SEM and XRD. The benzaldehyde yield reached 16.9% and selectivity reached 72.5% under the preliminary exploration operation conditions .