CAJ | 학술논문

开发了钒催化氧化胺、醇和胺直接合成亚胺催化体系，无须额外的添加剂或促进剂，空气作为环境友好的氧源，温和条件下，能高收率地得到各种对称和非对称亚胺，并且催化剂非常容易制备和使用。该催化体系对含杂原子亚胺的合成也非常有效。
개발료범최화양화알、순화알직접합성아알최화체계，무수액외적첨가제혹촉진제，공기작위배경우호적양원，온화조건하，능고수솔지득도각충대칭화비대칭아알，병차최화제비상용역제비화사용。해최화체계대함잡원자아알적합성야비상유효。
The direct synthesis of imines from amines or alcohols and amines by vanadium catalyzed aerobic oxidation was developed. Without an additive or promoter, various symmetrical and unsymmetrical imines were obtained in good to excellent yields under mild conditions with air as an environmen‐tally benign oxidant. The catalyst is very easy to prepare and use, and this catalytic system is also effective for the synthesis of heteroatom‐containing imines.