天然气化工
天然氣化工
천연기화공
NATURAL GAS CHEMICAL INDUSTRY
2014年
6期
21-24
,共4页
煤矸石%聚甲醛%改性%韧性
煤矸石%聚甲醛%改性%韌性
매안석%취갑철%개성%인성
coal gangue%polyoxymethylene(POM)%modification%toughness
将煤矸石煅烧处理,并将之填加进聚甲醛树脂中,以改进聚甲醛树脂的韧性,既改善了聚甲醛树脂的力学性能,又拓宽了煤矸石的利用途径。实验确定适宜的煤矸石改性聚甲醛工艺条件为:煤矸石研磨粒度为38μm,煅烧温度为800℃,加入煤矸石质量0.5%的硅烷偶联剂KH-550溶液(mKH-550:m 乙醇:m 水=20:72:8),烘干温度为120℃,煤矸石加入量为聚甲醛树脂质量的20%。通过拉力试验机和悬臂梁缺口冲击强度试验机对聚甲醛树脂的抗拉强度和缺口冲击强度进行了测定,结果表明,煤矸石颗粒的加入可以改善聚甲醛树脂的韧性,在优化的工艺条件下,聚甲醛树脂的拉伸强度为46MPa,缺口冲击强度为86J/m。
將煤矸石煅燒處理,併將之填加進聚甲醛樹脂中,以改進聚甲醛樹脂的韌性,既改善瞭聚甲醛樹脂的力學性能,又拓寬瞭煤矸石的利用途徑。實驗確定適宜的煤矸石改性聚甲醛工藝條件為:煤矸石研磨粒度為38μm,煅燒溫度為800℃,加入煤矸石質量0.5%的硅烷偶聯劑KH-550溶液(mKH-550:m 乙醇:m 水=20:72:8),烘榦溫度為120℃,煤矸石加入量為聚甲醛樹脂質量的20%。通過拉力試驗機和懸臂樑缺口遲擊彊度試驗機對聚甲醛樹脂的抗拉彊度和缺口遲擊彊度進行瞭測定,結果錶明,煤矸石顆粒的加入可以改善聚甲醛樹脂的韌性,在優化的工藝條件下,聚甲醛樹脂的拉伸彊度為46MPa,缺口遲擊彊度為86J/m。
장매안석단소처리,병장지전가진취갑철수지중,이개진취갑철수지적인성,기개선료취갑철수지적역학성능,우탁관료매안석적이용도경。실험학정괄의적매안석개성취갑철공예조건위:매안석연마립도위38μm,단소온도위800℃,가입매안석질량0.5%적규완우련제KH-550용액(mKH-550:m 을순:m 수=20:72:8),홍간온도위120℃,매안석가입량위취갑철수지질량적20%。통과랍력시험궤화현비량결구충격강도시험궤대취갑철수지적항랍강도화결구충격강도진행료측정,결과표명,매안석과립적가입가이개선취갑철수지적인성,재우화적공예조건하,취갑철수지적랍신강도위46MPa,결구충격강도위86J/m。
Calcined coal gangue was used to modify polyoxymethylene (POM), which not only toughened POM, but also developed a new application of coal gangue. Suitable conditions were determined experimentally as follows: the coal gangue was pestled to 38μm, then calcined at 800℃, mixed with silane coupling agent KH-550 solution (mKH-550:mEtOH:mH2O=20:72:8) in a dosage of 0.5% based on coal gangue mass, and dried at 120℃, then the dried coal gangue was mixed with POM in a mass ratio of the dried coal gangue to POM of 20%. Tensile strength and notch impact strength were tested by universal tensile testing machine and the Izod notched impact strength testing machine, respectively. The results showed that coal gangue could toughen POM, and the tensile strength and notch impact strength of POM processed under the optimum conditions reached 46MPa and 86J/m, respectively.