有色金属科学与工程
有色金屬科學與工程
유색금속과학여공정
JIANGXI NONFERROUS METALS
2014年
6期
132-136
,共5页
王华生%刘祖文%朱强%肖子捷%张念
王華生%劉祖文%硃彊%肖子捷%張唸
왕화생%류조문%주강%초자첩%장념
离子型稀土%原地浸矿%氮化物%空间分布%特征分析
離子型稀土%原地浸礦%氮化物%空間分佈%特徵分析
리자형희토%원지침광%담화물%공간분포%특정분석
ion adsorption rare-earth%in-situ leaching mining%nitrides%spatial distribution%characteristics analysis
由于南方离子型稀土在开采中使用大量铵盐作为浸矿剂,导致矿区土壤中氮化物含量严重超标,附近水体严重污染。通过建立土柱实验模型,测定不同时期不同深度稀土土壤中铵态氮、硝态氮和总氮的含量,研究了稀土土壤中氮化物的空间分布特征。实验结果表明,在不同淋洗水量条件下,表层稀土土壤中铵态氮和总氮含量降低明显,而硝态氮含量变化不明显,但深层土壤中铵态氮和总氮含量低且基本保持不变,硝态氮含量也没有明显变化。表明铵根离子的淋失是土壤和地下水污染的主要形式。研究结果为有效控制南方尤其是赣南离子型稀土矿土壤及水体氮化物污染奠定理论与技术基础。
由于南方離子型稀土在開採中使用大量銨鹽作為浸礦劑,導緻礦區土壤中氮化物含量嚴重超標,附近水體嚴重汙染。通過建立土柱實驗模型,測定不同時期不同深度稀土土壤中銨態氮、硝態氮和總氮的含量,研究瞭稀土土壤中氮化物的空間分佈特徵。實驗結果錶明,在不同淋洗水量條件下,錶層稀土土壤中銨態氮和總氮含量降低明顯,而硝態氮含量變化不明顯,但深層土壤中銨態氮和總氮含量低且基本保持不變,硝態氮含量也沒有明顯變化。錶明銨根離子的淋失是土壤和地下水汙染的主要形式。研究結果為有效控製南方尤其是贛南離子型稀土礦土壤及水體氮化物汙染奠定理論與技術基礎。
유우남방리자형희토재개채중사용대량안염작위침광제,도치광구토양중담화물함량엄중초표,부근수체엄중오염。통과건립토주실험모형,측정불동시기불동심도희토토양중안태담、초태담화총담적함량,연구료희토토양중담화물적공간분포특정。실험결과표명,재불동림세수량조건하,표층희토토양중안태담화총담함량강저명현,이초태담함량변화불명현,단심층토양중안태담화총담함량저차기본보지불변,초태담함량야몰유명현변화。표명안근리자적림실시토양화지하수오염적주요형식。연구결과위유효공제남방우기시공남리자형희토광토양급수체담화물오염전정이론여기술기출。
Nitride content in soil in mining area is abnormally high and the water nearby is badly polluted due to the use of large amounts of ammonium as a leaching agent during mining south ion-type rare earth. Through the establishment of experimental model of soil column and the determination of ammonium nitrogen and nitrate nitrogen and total nitrogen content in soil at different times in different depth, the temporal distribution characteristics of nitrides in the soil of south ion-type rare earth is studied. The results show that, under the condition of different water baths, surface soil ammonium nitrogen and total nitrogen in rare earth content reduce significantly, while nitrate-nitrogen content changes little. In deeper soil, the concentrations of ammonium nitrogen and total nitrogen remain unchanged low and the concentration of nitrate-nitrogen changes little as well, which implies that ammonium ions leaching are the main pollution form of soil and groundwater. These results will provide theoretical and technological foundation to control nitrides pollution in south ion-type of rare-earth and water body efficiently.