电子显微学报
電子顯微學報
전자현미학보
JOURNAL OF CHINESE ELECTRON MICROSCOPY SOCIETY
2014年
6期
495-498
,共4页
司尚禹%张成俊%李秀慧%吕文明%王宜良%张永成%叶万能%卢朝靖
司尚禹%張成俊%李秀慧%呂文明%王宜良%張永成%葉萬能%盧朝靖
사상우%장성준%리수혜%려문명%왕의량%장영성%협만능%로조정
0.88PMN-0.12PT%透明陶瓷%铁电体%扫描电子显微镜%透射电子显微镜
0.88PMN-0.12PT%透明陶瓷%鐵電體%掃描電子顯微鏡%透射電子顯微鏡
0.88PMN-0.12PT%투명도자%철전체%소묘전자현미경%투사전자현미경
0.88PMN-0.12PT%transparent ceramics%ferroelectric%scanning electron microscopy%transmission electron microscopy
用传统的无压烧结工艺制备出稀土元素 La 掺杂的高度透明纯钙钛矿相0?88Pb ( Mg1/3 Nb2/3) O3?0?12PbTiO3(简称0?88PMN?0?12PT)铁电陶瓷。当陶瓷样品厚度为0?8 mm时,在1550 nm处透光率达67%,接近其理论极限。电滞回线测量结果表明该组分透明陶瓷为典型的弛豫铁电体。显微结构观察结果表明陶瓷非常致密,晶粒排列规则,晶界结合强度高,多呈穿晶断裂,晶界干净,且厚度<2 nm。
用傳統的無壓燒結工藝製備齣稀土元素 La 摻雜的高度透明純鈣鈦礦相0?88Pb ( Mg1/3 Nb2/3) O3?0?12PbTiO3(簡稱0?88PMN?0?12PT)鐵電陶瓷。噹陶瓷樣品厚度為0?8 mm時,在1550 nm處透光率達67%,接近其理論極限。電滯迴線測量結果錶明該組分透明陶瓷為典型的弛豫鐵電體。顯微結構觀察結果錶明陶瓷非常緻密,晶粒排列規則,晶界結閤彊度高,多呈穿晶斷裂,晶界榦淨,且厚度<2 nm。
용전통적무압소결공예제비출희토원소 La 참잡적고도투명순개태광상0?88Pb ( Mg1/3 Nb2/3) O3?0?12PbTiO3(간칭0?88PMN?0?12PT)철전도자。당도자양품후도위0?8 mm시,재1550 nm처투광솔체67%,접근기이론겁한。전체회선측량결과표명해조분투명도자위전형적이예철전체。현미결구관찰결과표명도자비상치밀,정립배렬규칙,정계결합강도고,다정천정단렬,정계간정,차후도<2 nm。
High transparent La?doped 0?88Pb(Mg1/3Nb2/3)O3?0?12PbTiO3(0?88PMN?0?12PT) ceramics with pure perovskite phase were prepared by a conventional sintering process. When the thickness is 0?8 mm, the optical transmission of the 0?88PMN?0?12PT transparent ceramics reaches 67 % at the wavelength of 1550 nm, which is very close to its theoretical limitation. P?E loops show that the transparent ceramics are typical relaxor ferroelectric materials. Microstructure observations indicate the following characteristics:high density, homogeneous grain distribution, transgranular fracture, closely combined grains, and thin and clean gain boundaries.