中国油脂
中國油脂
중국유지
CHINA OILS AND FATS
2014年
12期
46-48
,共3页
麻文杰%夏勇%杨晶%李妮%周尽花%孙汉洲
痳文傑%夏勇%楊晶%李妮%週儘花%孫漢洲
마문걸%하용%양정%리니%주진화%손한주
桐油酸缩水甘油酯%桐油%桐油酸钾%环氧氯丙烷%两步法
桐油痠縮水甘油酯%桐油%桐油痠鉀%環氧氯丙烷%兩步法
동유산축수감유지%동유%동유산갑%배양록병완%량보법
eleostearic glycidyl ester%tung oil%eleostearic potassium%epoxy chloropropane%two-step method
研究了两步法合成桐油酸缩水甘油酯的主要反应条件,并用傅里叶变换红外光谱对目标产物进行了鉴定。结果表明：40 g桐油在KOH用量为8.5 g、采用90%甲醇为溶剂反应2 h的条件下,桐油酸钾的收率达到81%；在桐油酸钾与环氧氯丙烷摩尔比1∶4、反应时间4 h的条件下,桐油酸缩水甘油酯的收率可达92%,环氧值为4.7,接近理论环氧值4.8。
研究瞭兩步法閤成桐油痠縮水甘油酯的主要反應條件,併用傅裏葉變換紅外光譜對目標產物進行瞭鑒定。結果錶明：40 g桐油在KOH用量為8.5 g、採用90%甲醇為溶劑反應2 h的條件下,桐油痠鉀的收率達到81%；在桐油痠鉀與環氧氯丙烷摩爾比1∶4、反應時間4 h的條件下,桐油痠縮水甘油酯的收率可達92%,環氧值為4.7,接近理論環氧值4.8。
연구료량보법합성동유산축수감유지적주요반응조건,병용부리협변환홍외광보대목표산물진행료감정。결과표명：40 g동유재KOH용량위8.5 g、채용90%갑순위용제반응2 h적조건하,동유산갑적수솔체도81%；재동유산갑여배양록병완마이비1∶4、반응시간4 h적조건하,동유산축수감유지적수솔가체92%,배양치위4.7,접근이론배양치4.8。
The synthesis conditions of eleostearic glycidyl ester ( EGE ) were investigated by two -step method, and the product was confirmed by FT-IR. The results showed that the yield of eleostearic po-tassium could reach 81% under the conditions of tung oil 40 g, potassium hydroxide dosage 8. 5 g, reac-tion time 2 h, with 90% methanol as solution;the yield of EGE could reach 92% and its epoxy value was 4 . 7 ( close to the theoretical value 4 . 8 ) when molar ratio of eleostearic potassium to epoxy chloropropane and reaction time were 1∶4 and 4 h, respectively.
