电源技术
電源技術
전원기술
CHINESE JOURNAL OF POWER SOURCES
2014年
12期
2251-2252,2295
,共3页
孙百虎%赵菁%尚平
孫百虎%趙菁%尚平
손백호%조정%상평
锂离子电池电解液%过充保护添加剂%电化学性能
鋰離子電池電解液%過充保護添加劑%電化學性能
리리자전지전해액%과충보호첨가제%전화학성능
lithium-ion battery electrolyte%overcharge protection additives%electrochemical performance
作为锂离子电池的基本组成要素之一,电解液的基本特性直接影响着锂离子电池的循环特性、热稳定性和安全性。因此,利用添加剂来提高电解液的防过充能力成了改善电解液性能的重要方式。常用的添加剂主要有两类:氧化还原添加剂和电聚合添加剂。选取二甲氧基硝基苯类作为防过充添加剂。研究发现,该类添加剂的防过充能力好且具有很好的循环性能,能明显改善锂电池的循环性能和高低温性能。
作為鋰離子電池的基本組成要素之一,電解液的基本特性直接影響著鋰離子電池的循環特性、熱穩定性和安全性。因此,利用添加劑來提高電解液的防過充能力成瞭改善電解液性能的重要方式。常用的添加劑主要有兩類:氧化還原添加劑和電聚閤添加劑。選取二甲氧基硝基苯類作為防過充添加劑。研究髮現,該類添加劑的防過充能力好且具有很好的循環性能,能明顯改善鋰電池的循環性能和高低溫性能。
작위리리자전지적기본조성요소지일,전해액적기본특성직접영향착리리자전지적순배특성、열은정성화안전성。인차,이용첨가제래제고전해액적방과충능력성료개선전해액성능적중요방식。상용적첨가제주요유량류:양화환원첨가제화전취합첨가제。선취이갑양기초기분류작위방과충첨가제。연구발현,해류첨가제적방과충능력호차구유흔호적순배성능,능명현개선리전지적순배성능화고저온성능。
As one of the essential component of lithium-ion batteries:cycle characteristics, thermal stability and safety of lithium ion battery were directly affected by the basic characteristics of the electrolyte. Therefore, it was an important way that using of additives to improve the electrolyte's ability of overcharging. There were two types of commonly used additives:redox additive and electric polymeric additive. Dimethoxy nitrobenzene was selected as anti-over-charge additives. The study found that such additives were with good anti-overcharge ability and good cycle performance, and cycling performance and high temperature performance of lithium batteries could be significantly improved .