当代化工
噹代化工
당대화공
CONTEMPORARY CHEMICAL INDUSTRY
2014年
12期
2493-2496
,共4页
活性炭%活化改性%超级电容器%性能
活性炭%活化改性%超級電容器%性能
활성탄%활화개성%초급전용기%성능
Activated carbon%Modification%Super capacitor%Performance
以神华宁煤集团优质太西煤为原料,经物理化学法在800~850℃条件下活化处理,制备出超级电容器用煤基活性炭,并对改性前后活性炭的孔结构和形态进行表征。通过循环伏安、恒流充放电等测试手段,对该样品作为超级电容器电极材料而制备的电容器特性及其比电容进行研究。结果表明,以本实验所得太西煤基活性炭为原料制备的超级电容器电极抗化学腐蚀性能强、热膨胀系数较小、密度低,且具有优良的导热和大电流导电性能。
以神華寧煤集糰優質太西煤為原料,經物理化學法在800~850℃條件下活化處理,製備齣超級電容器用煤基活性炭,併對改性前後活性炭的孔結構和形態進行錶徵。通過循環伏安、恆流充放電等測試手段,對該樣品作為超級電容器電極材料而製備的電容器特性及其比電容進行研究。結果錶明,以本實驗所得太西煤基活性炭為原料製備的超級電容器電極抗化學腐蝕性能彊、熱膨脹繫數較小、密度低,且具有優良的導熱和大電流導電性能。
이신화저매집단우질태서매위원료,경물이화학법재800~850℃조건하활화처리,제비출초급전용기용매기활성탄,병대개성전후활성탄적공결구화형태진행표정。통과순배복안、항류충방전등측시수단,대해양품작위초급전용기전겁재료이제비적전용기특성급기비전용진행연구。결과표명,이본실험소득태서매기활성탄위원료제비적초급전용기전겁항화학부식성능강、열팽창계수교소、밀도저,차구유우량적도열화대전류도전성능。
Taking high-quality Taixi coal of Shenhua Ningxia Coal Group as raw material, the coal-based activated carbon(AC) for super capacitor was prepared by activation treatment at 800 ~ 850 ℃ with the physical-chemical process. And the pore size and morphology of activated carbon before and after the modification were characterized. Characteristics and specific capacitance of the capacitor prepared by using above activated carbon as the super capacitor electrode were studied with the testing methods of cyclic voltammetry and constant current charging-discharging. The results show that the activated carbon super capacitor electrode prepared from high-quality Taixi coal has better chemical corrosion resistance, smaller thermal expansion coefficient, lower density and better thermal conductivity and higher current electrical conductivity.