CAJ | 학술논문

该文以甲苯为焦油模型化合物，利用生物质焦炭诱导其转化合成气，探讨加热方式和通入CO2对甲苯转化的影响。结果表明：同等工况下，微波加热（microwave heating，MH）下甲苯转化率高于常规加热（electrical heating，EH），甲苯转化率最大差值为15.58%。通入CO2可促进甲苯转化，MH和EH下分别在CO2流量为80和40 mL/min达到最高转化率93.73%和82.13%。引入CO2可调控甲苯定向制备合成气，且对生物质焦炭造成碳损耗。损耗碳可转化合成气，且CO2通入量越高，其贡献越大。MH下合成气最大产率为173.66 mL/min，为裂解反应的5.68倍。甲苯裂解率持续降至49.0%，之后趋于稳定。甲苯重整转化率维持较高水平，140 min后开始减弱，同时合成气收率平缓降低。该文研究结果对高效利用焦油和减排CO2有借鉴意义。
해문이갑분위초유모형화합물，이용생물질초탄유도기전화합성기，탐토가열방식화통입CO2대갑분전화적영향。결과표명：동등공황하，미파가열（microwave heating，MH）하갑분전화솔고우상규가열（electrical heating，EH），갑분전화솔최대차치위15.58%。통입CO2가촉진갑분전화，MH화EH하분별재CO2류량위80화40 mL/min체도최고전화솔93.73%화82.13%。인입CO2가조공갑분정향제비합성기，차대생물질초탄조성탄손모。손모탄가전화합성기，차CO2통입량월고，기공헌월대。MH하합성기최대산솔위173.66 mL/min，위렬해반응적5.68배。갑분렬해솔지속강지49.0%，지후추우은정。갑분중정전화솔유지교고수평，140 min후개시감약，동시합성기수솔평완강저。해문연구결과대고효이용초유화감배CO2유차감의의。
The quality of gaseous products can be deteriorated by tar, CO2 and other impurities during the process of biomass gasification. Based on the those impurities analysis, tar conversion by CO2 is performed in this paper. Toluene was chosen as a model compound in this study, and it was used for converting into syngas production over a biomass-derived char. Biomass char is obtained from the pyrolysis of corn straw at a microwave-assisted experimental system. The influences of heating method includes microwave heating (MH) and electrical heating (EH) as well as CO2 flow rate on toluene conversion, syngas yield and carbon loss. The results show that toluene conversion from microwave heating is significantly higher than that from electrical heating under the same circumstances. And it is revealed that a maximum difference of toluene conversion between microwave heating and electrical heating is reached up to 15.58%at CO2 flow rate of 80 mL/min. When a certain amount of CO2 is imported, toluene conversion can be improved effectively. The highest toluene conversion of 93.73%is achieved under microwave heating at CO2 flow rate of 80 mL/min, while toluene conversion under electrical heating is reached a peak of 82.13%, corresponding to CO2 flow rate of 40 mL/min. Moreover, the introduction of CO2 can regulate the conversion of toluene into syngas production with a suitable ratio of H2 and CO. At the same time, an excess of CO2 can result in a loss of carbon contained in biomass-derived char. The carbon consumed through the gasification of CO2 can be converted into part of syngas production, which can impose a direct contribution to total syngas yield. With the increase of CO2 flow rate, a higher syngas yield from carbon consumption is achieved. The maximum contribution of carbon consumption to syngas yield is 15.40% under microwave heating at CO2 flow rate of 120 mL/min. According to the results, it is found that the highest yield of syngas derived from toluene reforming by CO2 under microwave heating is 173.66 mL/min when CO2 flow rate is 80 mL/min. And the yield mentioned above is 5.68 times that of syngas obtained from toluene cracking in the absence of CO2. A decrease in the conversion of toluene cracking is revealed, with the advancement of cracking experiment. And continuous decrease in toluene conversion occurred in cracking experiment until the conversion of toluene cracking drops below 49.0%. Afterwards, a stable phase of toluene conversion is seen in toluene cracking. It is fond that the conversion obtained from toluene reforming is maintained at a higher level, compared to that from toluene cracking. After toluene reforming conducted for 140 min, a decrease in toluene conversion is emerged. At the same time, a gentle decrease in the yield of syngas produced from toluene reforming is observed after 140 min. The conclusions of this study have a significant effect on efficient disposal and utilization of tar from biomass gasification. This research can also provide beneficial reference to the emission of CO2.