石油学报(石油加工)
石油學報(石油加工)
석유학보(석유가공)
ACTA PETROLEI SINICA(PETROLEUM PROCESSING SECTION)
2014年
6期
1119-1127
,共9页
桑小义%李会峰%李明丰%李大东
桑小義%李會峰%李明豐%李大東
상소의%리회봉%리명봉%리대동
含氧化合物%加氢脱氧%催化剂%失活%稳定性
含氧化閤物%加氫脫氧%催化劑%失活%穩定性
함양화합물%가경탈양%최화제%실활%은정성
oxygenic compounds%hydrodeoxygenation%catalyst%deactivation%stability
随着石油资源储量的减少,生物油作为石油替代能源备受人们的关注。生物油中含有较多的含氧化合物,氧质量分数一般超过30%。因此其热值较低,热稳定性较差,须对其进行加氢精制以脱除其中的氧。加氢脱氧(HDO )是对生物油进行提质的有效途径,反应过程中常用的催化剂为传统的硫化态加氢催化剂或还原态金属催化剂。简单概述了含氧化合物加氢脱氧催化剂的类型、催化剂失活的原因及提高催化剂稳定性的方法,并就未来研究方向和提高催化剂性能的改进措施提出了建议。
隨著石油資源儲量的減少,生物油作為石油替代能源備受人們的關註。生物油中含有較多的含氧化閤物,氧質量分數一般超過30%。因此其熱值較低,熱穩定性較差,鬚對其進行加氫精製以脫除其中的氧。加氫脫氧(HDO )是對生物油進行提質的有效途徑,反應過程中常用的催化劑為傳統的硫化態加氫催化劑或還原態金屬催化劑。簡單概述瞭含氧化閤物加氫脫氧催化劑的類型、催化劑失活的原因及提高催化劑穩定性的方法,併就未來研究方嚮和提高催化劑性能的改進措施提齣瞭建議。
수착석유자원저량적감소,생물유작위석유체대능원비수인문적관주。생물유중함유교다적함양화합물,양질량분수일반초과30%。인차기열치교저,열은정성교차,수대기진행가경정제이탈제기중적양。가경탈양(HDO )시대생물유진행제질적유효도경,반응과정중상용적최화제위전통적류화태가경최화제혹환원태금속최화제。간단개술료함양화합물가경탈양최화제적류형、최화제실활적원인급제고최화제은정성적방법,병취미래연구방향화제고최화제성능적개진조시제출료건의。
As the oil reserves are decreasing , bio‐oil as an alternative fuel source has attracted much attention .Bio‐oil contains a lot of oxygenic compounds and the oxygen content is generally more than 30% , leading to its low heating value and thermal instability , so it must be hydrotreated to remove the oxygen .Hydrodeoxygenation (HDO) is an effective way to upgrading bio‐oil .Catalysts for HDO are the traditional hydrodesulphurization (HDS ) catalysts , such as Co‐MoS2/Al2 O3 or metal catalysts .The type of catalysts used for bio‐oil HDO , the reason of catalyst deactivation and the method to improve the stability of catalyst were reviewed , in addition , the future research direction and the effective way for improving the catalyst activity were proposed .