石油化工高等学校学报
石油化工高等學校學報
석유화공고등학교학보
JOURNAL OF PETROCHEMICAL UNIVERSITIES
2014年
6期
36-41,49
,共7页
孙乾%李兆敏%李松岩%李宾飞%张超
孫乾%李兆敏%李鬆巖%李賓飛%張超
손건%리조민%리송암%리빈비%장초
纳米SiO2%表面张力%界面流变性%微观模型%采收率
納米SiO2%錶麵張力%界麵流變性%微觀模型%採收率
납미SiO2%표면장력%계면류변성%미관모형%채수솔
Nano-SiO 2%Surface tension%Interfacial rheological property%Microscopic model%Oil recovery efficiency
针对普通泡沫稳定性差的缺点,在表面活性剂中加入纳米 SiO 2从而提高泡沫的稳定性。利用Tracker 全自动界面流变仪测量了复配体系的表面张力和界面扩张模量;利用可视化刻蚀模型,探明了不同驱替方式的剩余油分布状况;利用岩心实验,对比了两种不同泡沫体系岩心驱替效果。结果表明,纳米 SiO 2颗粒与 SDS 复配后,体系的起泡体积有所降低,但是泡沫稳定性明显增强;纳米 SiO 2颗粒加入到 SDS 溶液后对体系的表面张力影响不大,但是界面黏弹性显著增加;微观驱油实验和岩心驱替实验结果表明,复配泡沫体系可以加强对孔道内壁油的挤压、携带作用,提高岩心两端的压差,从而增加波及面积,提高采收率。
針對普通泡沫穩定性差的缺點,在錶麵活性劑中加入納米 SiO 2從而提高泡沫的穩定性。利用Tracker 全自動界麵流變儀測量瞭複配體繫的錶麵張力和界麵擴張模量;利用可視化刻蝕模型,探明瞭不同驅替方式的剩餘油分佈狀況;利用巖心實驗,對比瞭兩種不同泡沫體繫巖心驅替效果。結果錶明,納米 SiO 2顆粒與 SDS 複配後,體繫的起泡體積有所降低,但是泡沫穩定性明顯增彊;納米 SiO 2顆粒加入到 SDS 溶液後對體繫的錶麵張力影響不大,但是界麵黏彈性顯著增加;微觀驅油實驗和巖心驅替實驗結果錶明,複配泡沫體繫可以加彊對孔道內壁油的擠壓、攜帶作用,提高巖心兩耑的壓差,從而增加波及麵積,提高採收率。
침대보통포말은정성차적결점,재표면활성제중가입납미 SiO 2종이제고포말적은정성。이용Tracker 전자동계면류변의측량료복배체계적표면장력화계면확장모량;이용가시화각식모형,탐명료불동구체방식적잉여유분포상황;이용암심실험,대비료량충불동포말체계암심구체효과。결과표명,납미 SiO 2과립여 SDS 복배후,체계적기포체적유소강저,단시포말은정성명현증강;납미 SiO 2과립가입도 SDS 용액후대체계적표면장력영향불대,단시계면점탄성현저증가;미관구유실험화암심구체실험결과표명,복배포말체계가이가강대공도내벽유적제압、휴대작용,제고암심량단적압차,종이증가파급면적,제고채수솔。
For the poor stability of general foams,Nano-SiO 2 was added into surfactant solution to increase the stability of foams.The surface tension and surface dilatational properties of the compounded system were measured by Tracker Interfacial Rheometer.The distribution of remaining oil and its oil displacement mechanism at each method of displacement were analyzed by microscopic model.The effect of oil recovery with two different foam systems was also studied by core experiments.It was proved that the increase of surface dilatational modules was the main reason for foam stability which can increase the sweep area and extrusion for oil on the channel wall.The core flooding results showed that both the oil recovery and the pressure drop increased with the SiO 2/SDS foam system.