林产化学与工业
林產化學與工業
림산화학여공업
CHEMISTRY AND INDUSTRY OF FOREST PRODUCTS
2014年
6期
69-74
,共6页
何水淋%李军%李智%徐峻%莫立焕
何水淋%李軍%李智%徐峻%莫立煥
하수림%리군%리지%서준%막립환
蔗渣浆%全无氯漂白%生产实践%可吸附有机卤化物
蔗渣漿%全無氯漂白%生產實踐%可吸附有機滷化物
자사장%전무록표백%생산실천%가흡부유궤서화물
bagasse pulp%OpQPo bleaching%production practice%AOX
总结了蔗渣浆清洁漂白生产线运行全无氯( OpQPo)流程时的小试实验、流程设计及生产实践经验。结果表明:未漂蔗渣浆经强化氧脱木质素处理之后,卡伯值从14.0~15.0降至7.0~7.3,脱木质素率达到50%~51%,白度则从42%~45%( ISO,下同)提高至58%~60%,生产运行效果优于小试实验;经后续预处理和压力过氧化氢漂白之后,纸浆产品白度达到80%以上,黏度在800 mL/g以上,产品质量明显优于传统氯气漂白-碱处理-次氯酸盐漂白( CEH)漂白;漂白过程不产生有毒有害的可吸附有机卤化物( AOX),且仅螯合预处理( Q)段有废水排放,废水色度低、污染负荷轻,易处理,可达标排放;相对传统漂白,新技术的实施并不会增加运行费用,主体设备投资约为1355万元人民币。
總結瞭蔗渣漿清潔漂白生產線運行全無氯( OpQPo)流程時的小試實驗、流程設計及生產實踐經驗。結果錶明:未漂蔗渣漿經彊化氧脫木質素處理之後,卡伯值從14.0~15.0降至7.0~7.3,脫木質素率達到50%~51%,白度則從42%~45%( ISO,下同)提高至58%~60%,生產運行效果優于小試實驗;經後續預處理和壓力過氧化氫漂白之後,紙漿產品白度達到80%以上,黏度在800 mL/g以上,產品質量明顯優于傳統氯氣漂白-堿處理-次氯痠鹽漂白( CEH)漂白;漂白過程不產生有毒有害的可吸附有機滷化物( AOX),且僅螯閤預處理( Q)段有廢水排放,廢水色度低、汙染負荷輕,易處理,可達標排放;相對傳統漂白,新技術的實施併不會增加運行費用,主體設備投資約為1355萬元人民幣。
총결료자사장청길표백생산선운행전무록( OpQPo)류정시적소시실험、류정설계급생산실천경험。결과표명:미표자사장경강화양탈목질소처리지후,잡백치종14.0~15.0강지7.0~7.3,탈목질소솔체도50%~51%,백도칙종42%~45%( ISO,하동)제고지58%~60%,생산운행효과우우소시실험;경후속예처리화압력과양화경표백지후,지장산품백도체도80%이상,점도재800 mL/g이상,산품질량명현우우전통록기표백-감처리-차록산염표백( CEH)표백;표백과정불산생유독유해적가흡부유궤서화물( AOX),차부오합예처리( Q)단유폐수배방,폐수색도저、오염부하경,역처리,가체표배방;상대전통표백,신기술적실시병불회증가운행비용,주체설비투자약위1355만원인민폐。
The experimental research, process design and production practice of total chlorine free OpQPo bleaching bagasse pulp were introduced in this paper. The results showed that Kappa number decreased from 14. 0-15. 0 to 7. 0-7. 3 with a 50% -51% removal of residual lignin, and pulp brightness increased from 42% - 45% ( ISO ) to 58% - 60% ( ISO ) after a strengthened oxygen delignification. The production practice showed a better performance than that in lab. After subsequent pretreatment and pressurized hydrogen peroxide bleaching, the final pulp brightness was beyond 80% and the viscosity was over 800 mL/g. The pulp quality was much better than traditional Chlorine-Alkali Extraction-Hypochlorite ( CEH) bleached pulp. Moreover, adsorbable organic halides ( AOX) was not generated any more in the bleaching process. The wastewater was only discharged in chelating pretreatment ( Q ) stage and easily treated to meet the critical discharge standard due to its lower chromaticity and lower pollution load. In contrast to the traditional bleaching, no additional investment was needed in this new technology. Besides, the production procedure was flexible and the operation was stable. The investment of main equipments was about ¥ 13. 55 million yuan.