CAJ | 학술논문

研究了在 N,N-二甲基甲酰胺（DMF）-离子液体[BMIm]Cl 混合溶剂中将蔗糖高效转化为5-羟甲基糠醛（5-HMF ）的反应。运用紫外-可见分光光度计对水解液中5-HMF 进行定量分析并计算其收率。考察了CrCl3·6H2O、AlCl3·6H2O、SnCl4·5H2O、FeCl3、CoCl2·6H2O、ZnCl2、CuCl2·2H2O、CaCl28种催化剂对反应的催化效果，结果表明AlCl3·6H2O催化效果最为明显。以AlCl3·6H2O为催化剂研究了不同反应条件如时间、温度、溶剂中DMF-[BMIm]Cl质量比、催化剂AlCl3·6H2O的用量对5-HMF收率的影响，得到的最佳条件为以0.5mmol蔗糖为反应物，0.4mmol AlCl3·6H2O 为催化剂，反应时间2h ，反应温度120℃，5g 质量比为85∶15的DMF-[BMIm]Cl混合溶剂，此条件下5-HMF收率最高可达63.4%。研究表明，DMF-[BMIm]Cl混合溶剂体系对蔗糖转化为5-HMF有一定的促进效果，在此溶剂体系中以AlCl3·6H2O为催化剂时可以得到较高的5-HMF产率。
연구료재 N,N-이갑기갑선알（DMF）-리자액체[BMIm]Cl 혼합용제중장자당고효전화위5-간갑기강철（5-HMF ）적반응。운용자외-가견분광광도계대수해액중5-HMF 진행정량분석병계산기수솔。고찰료CrCl3·6H2O、AlCl3·6H2O、SnCl4·5H2O、FeCl3、CoCl2·6H2O、ZnCl2、CuCl2·2H2O、CaCl28충최화제대반응적최화효과，결과표명AlCl3·6H2O최화효과최위명현。이AlCl3·6H2O위최화제연구료불동반응조건여시간、온도、용제중DMF-[BMIm]Cl질량비、최화제AlCl3·6H2O적용량대5-HMF수솔적영향，득도적최가조건위이0.5mmol자당위반응물，0.4mmol AlCl3·6H2O 위최화제，반응시간2h ，반응온도120℃，5g 질량비위85∶15적DMF-[BMIm]Cl혼합용제，차조건하5-HMF수솔최고가체63.4%。연구표명，DMF-[BMIm]Cl혼합용제체계대자당전화위5-HMF유일정적촉진효과，재차용제체계중이AlCl3·6H2O위최화제시가이득도교고적5-HMF산솔。
A series of experiments were used to study the conversion of sucrose into 5-hydroxymethylfurfural(5-HMF) in DMF-ionic liquid ([BMIm]CI) mixed solvent. UV-vis spectrophotometer was used for the quantitative analysis and the yield of 5-HMF calculation. The catalytic efficiencies of the eight metal chlorides (CrCl3·6H2O,AlCl3·6H2O,SnCl4·5H2O,FeCl3, CoCl2·6H2O,ZnCl2,CuCl2·2H2O,CaCl2) were studied. The results show that catalytic efficiency of AlCl3·6H2O is the highest. Different reaction conditions,such as time,temperature,quality ratio of DMF-[BMIm]Cl mixed solvent and catalyst dosage were investigated. The optimal condition for the highest 5-HMF yield,63.4%,is determined as follows:0.5mmol sucrose as reactants,0.4mmol AlCl3?6H2O as catalyst,reaction time 2h,reaction temperature 120℃ in 5g quality ratio of 85∶15 DMF-[BMIm]Cl mixed solvent. Research indicates that DMF-[BMIm]Cl mixed solvent system has certain promoting effect to the conversion of sucrose into 5-HMF,as catalyst AlCl3·6H2O can get higher 5-HMF yield in the solvent system.