中国矿业
中國礦業
중국광업
CHINA MINING MAGAZINE
2014年
12期
128-131
,共4页
颜小东%叶志文%崔晓荣%尤静娴
顏小東%葉誌文%崔曉榮%尤靜嫻
안소동%협지문%최효영%우정한
聚异丁烯丁二酸酐%山梨醇%乳化剂%乳化炸药
聚異丁烯丁二痠酐%山梨醇%乳化劑%乳化炸藥
취이정희정이산항%산리순%유화제%유화작약
polyisobutylene succinic anhydride%sorbitol%emulsifier%emulsion explosive
以聚异丁烯丁二酸酐、山梨醇为原料合成聚异丁烯丁二酸山梨醇酯乳化剂,用红外光谱对产物进行结构表征。并通过与Span‐80、T152作乳化力、乳胶基质形貌、乳胶基质稳定性的对比实验及该乳化剂在乳化炸药中的热安定性和爆炸性能来考察制备的乳化剂在乳化炸药中的应用情况。结果表明,该乳化剂的乳化力介于Span‐80和T152之间,但用该乳化剂制备的乳胶基质的粒径更小、稳定性更高,制备的乳化炸药热安定性好,爆炸性能优异。
以聚異丁烯丁二痠酐、山梨醇為原料閤成聚異丁烯丁二痠山梨醇酯乳化劑,用紅外光譜對產物進行結構錶徵。併通過與Span‐80、T152作乳化力、乳膠基質形貌、乳膠基質穩定性的對比實驗及該乳化劑在乳化炸藥中的熱安定性和爆炸性能來攷察製備的乳化劑在乳化炸藥中的應用情況。結果錶明,該乳化劑的乳化力介于Span‐80和T152之間,但用該乳化劑製備的乳膠基質的粒徑更小、穩定性更高,製備的乳化炸藥熱安定性好,爆炸性能優異。
이취이정희정이산항、산리순위원료합성취이정희정이산산리순지유화제,용홍외광보대산물진행결구표정。병통과여Span‐80、T152작유화력、유효기질형모、유효기질은정성적대비실험급해유화제재유화작약중적열안정성화폭작성능래고찰제비적유화제재유화작약중적응용정황。결과표명,해유화제적유화력개우Span‐80화T152지간,단용해유화제제비적유효기질적립경경소、은정성경고,제비적유화작약열안정성호,폭작성능우이。
Polyisobutylene succinic acid sorbitol ester was synthesized using polyisobutylene succinic anhydride and sorbitol as raw material .The structure of the product was characterized by infrared spectrum . To investigate the application of the emulsifier in emulsion explosives ,the emulsifying ability ,the morphology and stability of the emulsion matrix ,thermal stability and detonation performance preparaed with the product were tested .Compared to the emulsion and emulsion explosives prepared by Span‐80 and T152 as emulsifiers ,the rusults show that the emulsifying ability of the emulsifier is beween Span‐80 and T152 ,but smaller size of the emulsion matrix and longer storage period .Besides ,the detonation velocity is excellent ,the thermal stability in emulsion explosives is good .