CAJ | 학술논문

以无水乙醇为溶剂，在水热反应釜中利用邻菲啰啉与碱式碳酸铜于100℃反应制备配合物，通过XRD和IR对产品进行了表征。结果表明，当碱式碳酸铜与邻菲啰啉的摩尔比为1：2时，得到的深蓝色且具有规整形貌的配合物是以邻菲啰啉分子中两个氮原子上的孤对电子与Cu2＋离子发生配位而形成的。通过琼脂扩散抑菌法测定了配合物的抑菌性能，该系列配合物对大肠杆菌和金黄色葡萄球菌均具有较好的抑菌活性。
이무수을순위용제，재수열반응부중이용린비라람여감식탄산동우100℃반응제비배합물，통과XRD화IR대산품진행료표정。결과표명，당감식탄산동여린비라람적마이비위1：2시，득도적심람색차구유규정형모적배합물시이린비라람분자중량개담원자상적고대전자여Cu2＋리자발생배위이형성적。통과경지확산억균법측정료배합물적억균성능，해계렬배합물대대장간균화금황색포도구균균구유교호적억균활성。
A complex was successfully prepared by the reaction of 1,10-phenanthroline,basic carbonate copper in ethanol-water so-lution in hydrothermal reaction vessel at 100℃,and characterized by IR and X-ray single crystal structural analysis. The obtained com-posite was investigated by XRD and IR. The result show that the regular and deep blue composite was obtained under the conditions of molar ratio of basic carbonate copper to phenanthroline of 1:2 and the copper atom is coordinated with two N atoms of phenanthroline ligands. The agar diffusion antibacterial test shows that the complexes are active against the Staphylococcus aureus and Escherichia coli.