燃料化学学报
燃料化學學報
연료화학학보
JOURNAL OF FUEL CHEMISTRY AND TECHNOLOGY
2014年
12期
1416-1422
,共7页
赵冰%王嘉瑞%陈凡敏%王小悦%李小江
趙冰%王嘉瑞%陳凡敏%王小悅%李小江
조빙%왕가서%진범민%왕소열%리소강
高钠煤%赋存形态%脱钠%燃烧特性
高鈉煤%賦存形態%脫鈉%燃燒特性
고납매%부존형태%탈납%연소특성
hihg sodium coal%existingf orm%sodium er move%combustion charca teristci s
以五彩湾高钠煤为研究对象,根据煤中钠的赋存形态,分别研究了不同条件下水洗和水热处理两种方式对碱金属的脱除效果,同时考察了水热处理对煤燃烧特性的影响。结果表明,五彩湾煤中钠主要以水溶性钠盐存在;单纯水洗对Na的脱除效果不理想,并且工艺耗时长、耗水量大;水热处理脱钠效率高,钠脱除率高达90.5%,处理后的煤灰中Na2 O含量降至0.7%,属于低钠煤范围;水热处理后煤样的燃烧速率曲线移向低温区,燃烧特性优于原煤。
以五綵灣高鈉煤為研究對象,根據煤中鈉的賦存形態,分彆研究瞭不同條件下水洗和水熱處理兩種方式對堿金屬的脫除效果,同時攷察瞭水熱處理對煤燃燒特性的影響。結果錶明,五綵灣煤中鈉主要以水溶性鈉鹽存在;單純水洗對Na的脫除效果不理想,併且工藝耗時長、耗水量大;水熱處理脫鈉效率高,鈉脫除率高達90.5%,處理後的煤灰中Na2 O含量降至0.7%,屬于低鈉煤範圍;水熱處理後煤樣的燃燒速率麯線移嚮低溫區,燃燒特性優于原煤。
이오채만고납매위연구대상,근거매중납적부존형태,분별연구료불동조건하수세화수열처리량충방식대감금속적탈제효과,동시고찰료수열처리대매연소특성적영향。결과표명,오채만매중납주요이수용성납염존재;단순수세대Na적탈제효과불이상,병차공예모시장、모수량대;수열처리탈납효솔고,납탈제솔고체90.5%,처리후적매회중Na2 O함량강지0.7%,속우저납매범위;수열처리후매양적연소속솔곡선이향저온구,연소특성우우원매。
Considering the form of sodium existing in coal, series of water washing and hydrothermal treatments were used to remove alkali metals from a high sodium coal from Wucaiwan.The variation of combustion characteristics of coal after pretreatment was investigated.The results show that the sodium in the coal mainly exists as water-soluble form.The Na removal ratio by water washing treatment does not reach the expectation with the characteristics of time consuming and high water consumption.The hydrothermal treatment is effective in sodium removal as high as 90.5%, and Na2 O content in the ash decreases to 0.7% which belongs to the scope of low sodium lve el in coal sa h.The burnign curves of coal samples after hy drothermal treatment move to the low temperature zone, andt he combuts ion characteristics is improved compared with raw coal.