CAJ | 학술논문

以过硼酸钠为氧化剂，以C12烯烃为原料合成环氧十二烷。并做对比试验分析合成反应的影响因素。结果表明，采用0.02 mol过硼酸钠催化环氧化0.01 mol 1-十二烯时，最优反应条件是：温度控制在37~40℃，8 mL二氯甲烷，催化剂采取每2 h加入2 mmol（即3.0772 g/2 h）的加入方式，8 mL的乙酸酐采用逐滴滴加的方式，磁力搅拌反应30 h。
이과붕산납위양화제，이C12희경위원료합성배양십이완。병주대비시험분석합성반응적영향인소。결과표명，채용0.02 mol과붕산납최화배양화0.01 mol 1-십이희시，최우반응조건시：온도공제재37~40℃，8 mL이록갑완，최화제채취매2 h가입2 mmol（즉3.0772 g/2 h）적가입방식，8 mL적을산항채용축적적가적방식，자력교반반응30 h。
The experiment is to epoxide C12 olefin by sodium perborate to prepare epoxide compounds. The result showed that under the condition of 8 mL CH2 Cl2 ,37~40 ℃,8 mL( CH3 CO)2 O added in drops, 0. 02 mol NaBO3·4H2O added at a rate of 2 mmol/2 h(3. 077 2 g/2 h)and mechanical stirring for 30 h,the 0. 01 mol 1-dodecene can be epoxide to epoxy-dodecane at a high conversion.