应用化工
應用化工
응용화공
APPLIED CHEMICAL INDUSTRY
2014年
12期
2217-2221,2224
,共6页
余宗学%梁灵%何毅%马瑜%李飞%陈映晓
餘宗學%樑靈%何毅%馬瑜%李飛%陳映曉
여종학%량령%하의%마유%리비%진영효
缓蚀剂%电化学测试%扫描电镜%缓蚀性能%吸附类型
緩蝕劑%電化學測試%掃描電鏡%緩蝕性能%吸附類型
완식제%전화학측시%소묘전경%완식성능%흡부류형
corrosion inhibitor%electrochemical measurement%SEM%corrosion inhibition performance%adsorption type
成功合成了含咪唑环不对称双季铵盐,通过失重法、电化学阻抗谱、动电位扫描极化曲线、扫描电镜对合成产物在3% NaCl的饱和二氧化碳溶液中的缓蚀效率进行研究。结果表明,其在饱和二氧化碳溶液中对钢铁有着良好的缓蚀作用,缓蚀效率接近90%;运用Langmuir吸附等温式对吸附行为进行了拟合,表明其吸附类型符合Lang-muir吸附模型,吸附方式为化学吸附。
成功閤成瞭含咪唑環不對稱雙季銨鹽,通過失重法、電化學阻抗譜、動電位掃描極化麯線、掃描電鏡對閤成產物在3% NaCl的飽和二氧化碳溶液中的緩蝕效率進行研究。結果錶明,其在飽和二氧化碳溶液中對鋼鐵有著良好的緩蝕作用,緩蝕效率接近90%;運用Langmuir吸附等溫式對吸附行為進行瞭擬閤,錶明其吸附類型符閤Lang-muir吸附模型,吸附方式為化學吸附。
성공합성료함미서배불대칭쌍계안염,통과실중법、전화학조항보、동전위소묘겁화곡선、소묘전경대합성산물재3% NaCl적포화이양화탄용액중적완식효솔진행연구。결과표명,기재포화이양화탄용액중대강철유착량호적완식작용,완식효솔접근90%;운용Langmuir흡부등온식대흡부행위진행료의합,표명기흡부류형부합Lang-muir흡부모형,흡부방식위화학흡부。
The asymmetric bis quaternary ammonium salt containing imidazole ring was synthesised suc-cessfully. And weight-loss method,electrochemical impedance spectroscopy,potentiodynamic polarization curve,scanning electron microscopy was used to study on the inhibition efficiency of this product in sodi-um chloride solutions(3. 00%)bubbled with CO2-saturated. The result shows that it has good corrosion inhibition for the P110 steel in this solution,and the corrosion inhibition efficiency is closed to 90%. The adsorption behavior was fitted using the Langmuir adsorption isotherm,and showed that the adsorption type conforms to the Langmuir adsorption isotherm,its adsorption mode is chemical adsorption.