应用化工
應用化工
응용화공
APPLIED CHEMICAL INDUSTRY
2014年
12期
2186-2189
,共4页
帅超%廖运文%高和军%张娈娈%李宇飞
帥超%廖運文%高和軍%張孌孌%李宇飛
수초%료운문%고화군%장련련%리우비
介孔材料%亚甲基蓝%吸附
介孔材料%亞甲基藍%吸附
개공재료%아갑기람%흡부
mesoporous materias%methylene blue%adsorption
采用化学沉淀法制备了一系列的Zn改性氧化硅(0.1Zn-Si、0.2Zn-Si和0.4Zn-Si )和纯氧化硅(0.0Zn-Si)介孔材料,并探讨了介孔Zn-Si材料对亚甲基蓝( MB)的吸附行为。详细的考察了pH、时间和温度对吸附量性能的影响。结果表明,在酸性条件下,Zn-Si样品的吸附容量高于纯的 SiO2材料,特别是0.2Zn-Si样品的吸附量达到228.88 mg/g;实验数据表明,Zn-Si介孔材料对亚甲基蓝的吸附过程符合假二级动力学方程和Langmuir等温吸附模型。
採用化學沉澱法製備瞭一繫列的Zn改性氧化硅(0.1Zn-Si、0.2Zn-Si和0.4Zn-Si )和純氧化硅(0.0Zn-Si)介孔材料,併探討瞭介孔Zn-Si材料對亞甲基藍( MB)的吸附行為。詳細的攷察瞭pH、時間和溫度對吸附量性能的影響。結果錶明,在痠性條件下,Zn-Si樣品的吸附容量高于純的 SiO2材料,特彆是0.2Zn-Si樣品的吸附量達到228.88 mg/g;實驗數據錶明,Zn-Si介孔材料對亞甲基藍的吸附過程符閤假二級動力學方程和Langmuir等溫吸附模型。
채용화학침정법제비료일계렬적Zn개성양화규(0.1Zn-Si、0.2Zn-Si화0.4Zn-Si )화순양화규(0.0Zn-Si)개공재료,병탐토료개공Zn-Si재료대아갑기람( MB)적흡부행위。상세적고찰료pH、시간화온도대흡부량성능적영향。결과표명,재산성조건하,Zn-Si양품적흡부용량고우순적 SiO2재료,특별시0.2Zn-Si양품적흡부량체도228.88 mg/g;실험수거표명,Zn-Si개공재료대아갑기람적흡부과정부합가이급동역학방정화Langmuir등온흡부모형。
A series of Zn modified silicon oxide(0. 1Zn-Si,0. 2Zn-Si and 0. 4Zn-Si)mesoporous materi-als and pure silicon oxide(0. 0Zn-Si)had been prepared by chemical corprecipitation method,and the adsorption capacity of the Zn-Si mesoporous materials with respect to MB was investigated. The effects of initial solution pH,contact time and temperature on MB adsorption had been investigated. The results showed that Zn-Si have a superior adsorption capability compare with pure SiO2 under acid condition. Un-der certain conditions,the adsorption capability of MB on 0. 2Zn-Si can get 228. 88 mg/g. The pseudo-second-order model and Langmuir adsorption isotherm model could be well fit to the experimental data of adsorption MB onto Zn-Si samples.