有机硅材料
有機硅材料
유궤규재료
SILICONE MATERIAL
2014年
6期
415-421
,共7页
衣康酸双(十三氟辛基)酯%丙烯酸十三氟辛酯%氨基硅油%氟烷基烯酸酯
衣康痠雙(十三氟辛基)酯%丙烯痠十三氟辛酯%氨基硅油%氟烷基烯痠酯
의강산쌍(십삼불신기)지%병희산십삼불신지%안기규유%불완기희산지
bis(1H,1H,2H,2H-tridecafluorooctyl)methylenesuccinate%1H,1H,2H,2H-tridecafluo tridecafluorooctyl- 1-acrylate%amino functional silicone fluid%fluoroalkyl alkenylcarboxylic ester
以3-氨丙基甲基二乙氧基硅烷、二甲基二甲氧基硅烷为原料制得氨基硅油；以十三氟辛醇、衣康酸等为原料制得衣康酸双（十三氟辛基）酯；分别采用衣康酸双（十三氟辛基）酯、丙烯酸十三氟辛酯与氨基硅油中的伯氨基发生加成反应，制得2种含氟烯酸酯改性氨基硅油，并将其应用于涤纶织物的增深整理。研究了衣康酸双（十三氟辛基）酯改性氨基硅油中氟的质量分数和氨基的质量分数及整理工艺对涤纶织物增深整理效果的影响。衣康酸双（十三氟辛基）酯改性氨基硅油中增加氟的质量分数有利于增深率的提高，而增加氨基的质量分数却导致增深效果降低；丙烯酸十三氟辛酯改性氨基硅油对涤纶织物增深整理的最佳工艺条件为：整理剂浓度30 g/L，焙烘温度160℃，焙烘时间2 min，增深提升率达19.40%。两种改性氨基硅油对涤纶织物均有较好的增深作用。
以3-氨丙基甲基二乙氧基硅烷、二甲基二甲氧基硅烷為原料製得氨基硅油；以十三氟辛醇、衣康痠等為原料製得衣康痠雙（十三氟辛基）酯；分彆採用衣康痠雙（十三氟辛基）酯、丙烯痠十三氟辛酯與氨基硅油中的伯氨基髮生加成反應，製得2種含氟烯痠酯改性氨基硅油，併將其應用于滌綸織物的增深整理。研究瞭衣康痠雙（十三氟辛基）酯改性氨基硅油中氟的質量分數和氨基的質量分數及整理工藝對滌綸織物增深整理效果的影響。衣康痠雙（十三氟辛基）酯改性氨基硅油中增加氟的質量分數有利于增深率的提高，而增加氨基的質量分數卻導緻增深效果降低；丙烯痠十三氟辛酯改性氨基硅油對滌綸織物增深整理的最佳工藝條件為：整理劑濃度30 g/L，焙烘溫度160℃，焙烘時間2 min，增深提升率達19.40%。兩種改性氨基硅油對滌綸織物均有較好的增深作用。
이3-안병기갑기이을양기규완、이갑기이갑양기규완위원료제득안기규유；이십삼불신순、의강산등위원료제득의강산쌍（십삼불신기）지；분별채용의강산쌍（십삼불신기）지、병희산십삼불신지여안기규유중적백안기발생가성반응，제득2충함불희산지개성안기규유，병장기응용우조륜직물적증심정리。연구료의강산쌍（십삼불신기）지개성안기규유중불적질량분수화안기적질량분수급정리공예대조륜직물증심정리효과적영향。의강산쌍（십삼불신기）지개성안기규유중증가불적질량분수유리우증심솔적제고，이증가안기적질량분수각도치증심효과강저；병희산십삼불신지개성안기규유대조륜직물증심정리적최가공예조건위：정리제농도30 g/L，배홍온도160℃，배홍시간2 min，증심제승솔체19.40%。량충개성안기규유대조륜직물균유교호적증심작용。
Amino functional silicone fluid was prepared with 3-amino propyl methyldiethoxysilane and dimethyl dimethoxy silane as the starting materials. Meanwhile,bis(1H,1H,2H,2H-tridecafluorooctyl)meth-ylenesuccinate was prepared with 13 fluoro octanol and itaconate as the starting materials. Then 2 kinds of flu-oroalkyl modifying amino functional silicone fluid were obtained by reacting bis(1H,1H,2H,2H-tridecafluo-rooctyl)methylenesuccinate and 1H,1H,2H,2H-tridecafluorooctyl-1-acrylate with amino functional silicone fluid. The products were applied for darkening finishing on polyester fabrics. The effects of mass fraction of fluorine and amino in bis(1H,1H,2H,2H-tridecafluorooctyl)methylenesuccinate modified amino functional silicone fluid and its finishing technology on the deepening of the polyester fabric finishing were investigated. Results show that increasing the fluorine content in bis(1H,1H,2H,2H-tridecafluorooctyl)methylenesuccinate modified amino functional silicone fluid could increase the color-darkening,whereas increasing amino func-tional results in low color-darkening. The best finishing process of amino functional silicone fluid modified with 1H,1H,2H,2H-tridecafluorooctyl-1-acrylate is baking with 30 g/L of deepening agent at 160℃ for 2 min. As a result,the K/S value was increased up to 19. 40%. Both of the amino functional silicone fluids have better color-darkening effects.
