CAJ | 학술논문

通过测定含不同 H2O2浓度的纯水体系及硝基苯类化合物水样体系的废水化学需氧量（COD），分析发现硝基苯类化合物水样中 H2 O2对 COD 的测量存在正干扰，且具有很好的线性关系。在不引入新的干扰前提下，探讨了相应的 H2 O2消除方法。结果表明，当水样中 H2O2浓度475 mg·L－1，COD 值为747．6 mg·L－1时，改变水样 pH 值为碱性有利于 H2O2的去除；添加二氧化锰催化剂虽然能在较短时间内去除 H2 O2，但可能引入新的干扰物；添加过氧化氢酶在不引入新的干扰情况下可快速去除 H2 O2。当反应时间3 min，分别调节水样 pH 为12、添加二氧化锰、添加过氧化氢酶，水样中 H2 O2去除率为1．2％、45．6％、100％。在相同酶量下处理含不同浓度 H2 O2的水样，H2 O2均可在短时间内被除净。分析表明，添加过氧化氢酶可为快速、高效消除废水中未知浓度 H2O2对 CODCr测定的影响提供一条新的途径。
통과측정함불동 H2O2농도적순수체계급초기분류화합물수양체계적폐수화학수양량（COD），분석발현초기분류화합물수양중 H2 O2대 COD 적측량존재정간우，차구유흔호적선성관계。재불인입신적간우전제하，탐토료상응적 H2 O2소제방법。결과표명，당수양중 H2O2농도475 mg·L－1，COD 치위747．6 mg·L－1시，개변수양 pH 치위감성유리우 H2O2적거제；첨가이양화맹최화제수연능재교단시간내거제 H2 O2，단가능인입신적간우물；첨가과양화경매재불인입신적간우정황하가쾌속거제 H2 O2。당반응시간3 min，분별조절수양 pH 위12、첨가이양화맹、첨가과양화경매，수양중 H2 O2거제솔위1．2％、45．6％、100％。재상동매량하처리함불동농도 H2 O2적수양，H2 O2균가재단시간내피제정。분석표명，첨가과양화경매가위쾌속、고효소제폐수중미지농도 H2O2대 CODCr측정적영향제공일조신적도경。
The chemical oxygen demand( COD)for pure water and nitrobenzene waste water sample containing different content of H2 O2 was measured and the linear interference of H2 O2 concentration on COD test was studied. It shows that with increase of the H2 O2 ,the COD increases. Without new interference,the ways to suppress interference of H2 O2 on COD test were discussed including pH value,manganese dioxide catalyst,and catalase. Results show that the catalase eliminates the influence of H2O2on COD determination effectively,and the alkaline environment is in favor of removing the H2O2 to some extent,and manganese di-oxide catalyst can remove H2 O2 in short time but it may introduce new interferences. When the reaction time is 3 min,by adjus-ing initial liquid pH value of 12,adding manganese dioxide catalyst and catalase,respectively,the H2O2 removal rate can reach 1.2%,45.6% and 100%,indicating that catalase can conveniently remove H2O2 with unknown concentration,and suppress the interference of H2 O2 on COD test.