广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2014年
24期
74-76
,共3页
配位聚合物%水热合成%镍聚化合物
配位聚閤物%水熱閤成%鎳聚化閤物
배위취합물%수열합성%얼취화합물
coordination polymers%hydrothermal synthesis%nickel compound
在水热条件下,成功合成出一例新型镍配位聚合物(CPs),[Ni2(phen)2(BTC)(H2O)6]·2H2O (化合物1, phen=1,10-菲罗啉, BTC=1,2,4,5-均苯四甲酸)。 X-射线单晶衍射分析表明,化合物1属于三斜晶系, P1空间群,晶胞参数为a=7.3604(5)?, b=10.9871(7)?, c=12.1984(8)?,α=66.787(6)°,β=76.531(6)°,γ=70.716(6)°, Z=2。结构分析显示化合物1是一个二聚物,并且通过配位水分子和均苯四甲酸配体上的配位原子形成的氢键进一步形成3D的超分子结构。
在水熱條件下,成功閤成齣一例新型鎳配位聚閤物(CPs),[Ni2(phen)2(BTC)(H2O)6]·2H2O (化閤物1, phen=1,10-菲囉啉, BTC=1,2,4,5-均苯四甲痠)。 X-射線單晶衍射分析錶明,化閤物1屬于三斜晶繫, P1空間群,晶胞參數為a=7.3604(5)?, b=10.9871(7)?, c=12.1984(8)?,α=66.787(6)°,β=76.531(6)°,γ=70.716(6)°, Z=2。結構分析顯示化閤物1是一箇二聚物,併且通過配位水分子和均苯四甲痠配體上的配位原子形成的氫鍵進一步形成3D的超分子結構。
재수열조건하,성공합성출일례신형얼배위취합물(CPs),[Ni2(phen)2(BTC)(H2O)6]·2H2O (화합물1, phen=1,10-비라람, BTC=1,2,4,5-균분사갑산)。 X-사선단정연사분석표명,화합물1속우삼사정계, P1공간군,정포삼수위a=7.3604(5)?, b=10.9871(7)?, c=12.1984(8)?,α=66.787(6)°,β=76.531(6)°,γ=70.716(6)°, Z=2。결구분석현시화합물1시일개이취물,병차통과배위수분자화균분사갑산배체상적배위원자형성적경건진일보형성3D적초분자결구。
The new coordination polymers(CPs), one novel nickel compounds, [Ni2(phen)2(BTC)(H2O)6]· 2H2O (compound 1, phen=1,10-Phenanthroline hydrate, BTC=1,2,4,5-benzene-tetracarboxylic acid), were synthesized under hydrothermal conditions. Single-crystal X-ray diffraction analysis indicated that compound 1 was triclinic and crystallize in the P1 space group with a=7. 3604(5)?, b=10. 9871(7)?, c=12. 1984(8)?,α=66. 787(6)°,β=76. 531(6)°, γ=70. 716(6)°, and Z=2. Compound 1 was a dimer, which was further connected to a 3D supermolecular structure by hydrogen bonds between coordinated water moleculars and BTC ligands.
