CAJ | 학술논문

为了对退役硝化棉（ NC）基固体推进剂中黑索今（ RDX）等有效成分进行回收再利用，研究了实验室级别的现代超声辅助提取法（ UAE）、开放式聚焦微波辅助提取法（ MAE）、加压加热提取法（ PLE）及传统的索式提取法（ SE）、溶剂溶解水析出法（SDWP），用液相色谱法、红外光谱法对提取效果进行表征。结果表明，PLE的高压可防止硝化甘油（NG）的挥发和分解，用CH2 Cl2作提取剂，能很好溶解RDX等待测物、完全不溶解NC，使得提取物和NC容易分离，提取效率高、时间短，优于其他方法，有望实际应用于大量的退役NC基推进剂中RDX等有效组分的回收利用。
위료대퇴역초화면（ NC）기고체추진제중흑색금（ RDX）등유효성분진행회수재이용，연구료실험실급별적현대초성보조제취법（ UAE）、개방식취초미파보조제취법（ MAE）、가압가열제취법（ PLE）급전통적색식제취법（ SE）、용제용해수석출법（SDWP），용액상색보법、홍외광보법대제취효과진행표정。결과표명，PLE적고압가방지초화감유（NG）적휘발화분해，용CH2 Cl2작제취제，능흔호용해RDX등대측물、완전불용해NC，사득제취물화NC용역분리，제취효솔고、시간단，우우기타방법，유망실제응용우대량적퇴역NC기추진제중RDX등유효조분적회수이용。
In order to recycle and utilize useful component cyclotrimethylenetrinitramine ( RDX) in waste nitrocellulose( NC)?based propellant, the extraction methods of ultra sound?assisted extraction ( UAE ) , open?focus?microwave?assisted extraction (MAE), pressurized liquid extraction (PLE), soxlet's extraction (SE) and organic?solvent?dissolve?water?precipitation (SDWP) were studied in lab. The results, which were characterized by HPLC and IR, show that the method of PLE, in which CH2 Cl2 is used as extractant is efficient and time?saving compared with the other methods. In the method of PLE, the high pressure can pre?vent the volatilzation and decomposition of nitroglycerin (NG).The completely different dissolving performance of RDX and NC in CH2Cl2 is beneficial to seperation of them. PLE is expected to be practically applied to recycle and utilization of useful component RDX from a lot of waste NC based propellant.