中南大学学报(英文版)
中南大學學報(英文版)
중남대학학보(영문판)
JOURNAL OF CENTRAL SOUTH UNIVERSITY OF TECHNOLOGY(ENGLISH EDITION)
2014年
12期
4613-4622
,共10页
邓娜%崔文谦%王维维%张强%张于峰%马洪亭
鄧娜%崔文謙%王維維%張彊%張于峰%馬洪亭
산나%최문겸%왕유유%장강%장우봉%마홍정
co-pyrolysis%medical waste%tube for transfusion (TFT)%catheter%interaction
Thermal decomposition of 21 kinds of binary mixtures between typical medical compositions was investigated under nitrogen conditions by dynamic thermogravimetric analysis (TGA) at 25–800 °C. The weighed sum method (WSM) coupled with thermal analysis was applied to study the interaction between components. Then, co-pyrolysis kinetic model of the binary mixtures (tube for transfusion (TFT) and gauze) was established to verify the reliability of conclusions. The results show the follows. 1) Strong or weak interactions are shown between binary mixtures containing polyvinyl chloride (PVC),the main ingredient of TFT. The addition of other medical waste could enhance first stage decomposition of TFT. While, the secondary stage pyrolysis may be suppressed or enhanced or not affected by the addition. 2) There exists no interaction between catheter and other component, the DTG peak temperature representing CaCO3 decomposition in catheter fraction is obviously lower than that of pure catheter;while, the shape of DTG peak keeps unchanged. 3) No evident reaction occurs between the other mix-samples, it is considered that their co-pyrolysis characteristics are linear superposition of mono-component pyrolysis characteristics.