CAJ | 학술논문

采用微波均相沉淀法合成 CeO2/凹凸棒石复合材料；借助热重(TG)/差示扫描量热(DSC)分析仪、X 射线粉末衍射(XRD)、透射电子显微镜(TEM)附带能谱(EDS)仪、选区电子衍射(SAED)、拉曼(Raman)光谱和傅里叶红外光谱(FT-IR)等测试手段对复合材料进行表征；研究 CeO2负载量和反应温度对复合材料结构、形貌和催化氧化性能的影响，并且对复合材料的形成机理进行分析。结果表明：当CeO2负载量为50%(CeO2与凹凸棒石的质量分数)，微波反应温度为100℃时，经450℃煅烧，CeO2纳米颗粒可以较好地分散在凹凸棒石表面；当使用此复合材料作为催化剂，其对亚甲基蓝的脱色率可达到96%。
채용미파균상침정법합성 CeO2/요철봉석복합재료；차조열중(TG)/차시소묘량열(DSC)분석의、X 사선분말연사(XRD)、투사전자현미경(TEM)부대능보(EDS)의、선구전자연사(SAED)、랍만(Raman)광보화부리협홍외광보(FT-IR)등측시수단대복합재료진행표정；연구 CeO2부재량화반응온도대복합재료결구、형모화최화양화성능적영향，병차대복합재료적형성궤리진행분석。결과표명：당CeO2부재량위50%(CeO2여요철봉석적질량분수)，미파반응온도위100℃시，경450℃단소，CeO2납미과립가이교호지분산재요철봉석표면；당사용차복합재료작위최화제，기대아갑기람적탈색솔가체도96%。
CeO2/palygorskite composites were synthesized by the microwave homogeneous precipitation method. Thermogravimetry (TD)/differential scanning calorimetry (DSC) analysis, powder X-ray diffractometry (XRD), transmission electron microscopy (TEM) with energy-dispersive spectroscope (EDS), selected area electron diffraction (SAED), Raman spectroscopy and Fourier transform infrared spectrometer (FT-IR) tests were used to characterize the composites. The effects of CeO2 loading amount and reaction temperature on the structure, morphology and catalytic performance of the composites were investigated. The formation mechanism of the composite was also studied. The result shows that at CeO2 loading of 50% (mass fraction of CeO2 to polygorskite), microwave reaction temperature of 100℃and calcination temperature of 450℃, the CeO2 nanoparticles distribute well on the surface of the palygorskite. When the composite is used as the catalyst, the decolorization ratio of methylene blue can reach 96%.