功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2015年
3期
3069-3072
,共4页
赵燕春%袁小鹏%寇生中%赵志平%罗文涛%李春燕%袁子洲
趙燕春%袁小鵬%寇生中%趙誌平%囉文濤%李春燕%袁子洲
조연춘%원소붕%구생중%조지평%라문도%리춘연%원자주
非晶复合材料%形变诱导相变%半固态处理%组织%力学性能
非晶複閤材料%形變誘導相變%半固態處理%組織%力學性能
비정복합재료%형변유도상변%반고태처리%조직%역학성능
bulk amorphous composites%deformation induced transformation%semi-solid heat-treatment%micro-structure%mechanical property
利用“形变诱导相变机制”对非晶基体同时增强增韧,采用悬浮熔炼-铜模吸铸法制备了 Ti 基非晶复合材料.在此基础上,通过半固态处理工艺对凝固过程动力学控制优化组织,研究了半固态处理对试样的组织和力学行为的影响.结果表明,铸态试样组织为过冷奥氏体相、热致马氏体相和非晶复合结构,应力加载形变过程中通过形状记忆晶相 TRIP 效应对非晶基体增韧,表现为加工硬化行为.铸态试样的心部组织为较粗大的树枝晶,且生长不均匀;经半固态处理后,先析出相按照尖角溶解平面析出长大形式近球化,形成等轴晶,并在磁悬浮搅拌作用下均匀化,获得奥氏体相晶粒细小、圆整度高、组织致密,复合材料组织得到有效优化,(Ti0.5 Ni0.48 Co0.02)80 Cu20合金断裂强度和塑性变形量由2582 MPa 和15%分别提高至2745 MPa和21.5%.
利用“形變誘導相變機製”對非晶基體同時增彊增韌,採用懸浮鎔煉-銅模吸鑄法製備瞭 Ti 基非晶複閤材料.在此基礎上,通過半固態處理工藝對凝固過程動力學控製優化組織,研究瞭半固態處理對試樣的組織和力學行為的影響.結果錶明,鑄態試樣組織為過冷奧氏體相、熱緻馬氏體相和非晶複閤結構,應力加載形變過程中通過形狀記憶晶相 TRIP 效應對非晶基體增韌,錶現為加工硬化行為.鑄態試樣的心部組織為較粗大的樹枝晶,且生長不均勻;經半固態處理後,先析齣相按照尖角溶解平麵析齣長大形式近毬化,形成等軸晶,併在磁懸浮攪拌作用下均勻化,穫得奧氏體相晶粒細小、圓整度高、組織緻密,複閤材料組織得到有效優化,(Ti0.5 Ni0.48 Co0.02)80 Cu20閤金斷裂彊度和塑性變形量由2582 MPa 和15%分彆提高至2745 MPa和21.5%.
이용“형변유도상변궤제”대비정기체동시증강증인,채용현부용련-동모흡주법제비료 Ti 기비정복합재료.재차기출상,통과반고태처리공예대응고과정동역학공제우화조직,연구료반고태처리대시양적조직화역학행위적영향.결과표명,주태시양조직위과랭오씨체상、열치마씨체상화비정복합결구,응력가재형변과정중통과형상기억정상 TRIP 효응대비정기체증인,표현위가공경화행위.주태시양적심부조직위교조대적수지정,차생장불균균;경반고태처리후,선석출상안조첨각용해평면석출장대형식근구화,형성등축정,병재자현부교반작용하균균화,획득오씨체상정립세소、원정도고、조직치밀,복합재료조직득도유효우화,(Ti0.5 Ni0.48 Co0.02)80 Cu20합금단렬강도화소성변형량유2582 MPa 화15%분별제고지2745 MPa화21.5%.
Ti-based bulk amorphous composites,designed by deformation induced transformation effect to en-hance the strength and plasticity,were fabricated by suspend melting under an argon atmosphere using a copper mold.And semi-solid heat-treatment was chosen to control the solidification kinetics and optimize the micro-structure.The effect of semi-solid heat-treatment on microstructure and mechanical properties of Ti-based bulk amorphous composites were investigated.The results showed that the as-cast compounds microstructure were consist of the supercooled austenite phase,thermally-induced martensite phase and amorphous phase.As load-ing,the alloys were strengthened and toughed by TRIP effect,and exhibit a strongly work-hardening behavior. The as-cast microstructure of core region contains coarse dendrites with uneven growth.Nevertheless,the semi-solid heat-treated microstructure contains equiaxed grain with higher spheroidization,smaller and more uniform size.The spheroidal grain was formed by the sharp corner solution and plane precipitation growth mechanism. Therefore the composites microstructure was effectively optimized,as well as the comprehensive mechanical properties are further improved.After semi-solid heat-treated,fracture strength and plastic deformation of (Ti0.5Ni0.48Co0.02)80Cu20 were enhanced from 2 582 MPa and 15%,to 2 745 MPa and 21.5%.