CAJ | 학술논문

利用微波法分别一步合成谷氨酸氟硼酸离子液体和谷氨酸对甲苯磺酸离子液体，并应用到乙酸正丁酯酯化反应中。通过一系列平行反应研究了催化剂种类、催化剂质量、反应时间对酯化反应的影响。实验结果表明，以乙酸、正丁醇为原料，谷氨酸对甲苯磺酸离子液体催化效果最好，可替代硫酸、对甲苯磺酸等强酸。最佳反应条件为：醇酸物质的量的比为1∶1，催化剂质量为醋酸质量的1.3％，反应时间为45 m in ，酯化率可达到78.51％。
이용미파법분별일보합성곡안산불붕산리자액체화곡안산대갑분광산리자액체，병응용도을산정정지지화반응중。통과일계렬평행반응연구료최화제충류、최화제질량、반응시간대지화반응적영향。실험결과표명，이을산、정정순위원료，곡안산대갑분광산리자액체최화효과최호，가체대류산、대갑분광산등강산。최가반응조건위：순산물질적량적비위1∶1，최화제질량위작산질량적1.3％，반응시간위45 m in ，지화솔가체도78.51％。
The glutamic tetrofluoroborate and glutamic p‐Toluene sulfonicate ionic liquids were synthesized via a facile and fast microwave assisted method in one step ,which were applied to the esterification reaction of prepartion of n‐butyl acetate .Through a series of parallel experiments , the effects of kind and mass of catalyst , and reaction time on esterification reaction were investigated .The experimental results show that the glutamic p‐toluene sulfonicate ionic liquid exhibits best performance ,which may take the place of sulfuric and p‐toluene sulfonic acids .The optimization conditions of the reaction are :the molar ratio of n‐butyl alcohol and acetic acid=1∶1 ,the mass ratio of catalyst and acetic acid =1.3 :100 ,and reaction for 45 min ,finally ,the es‐terification ratio may reach 78.51% .