江苏科技大学学报(自然科学版)
江囌科技大學學報(自然科學版)
강소과기대학학보(자연과학판)
JOURNAL OF JIANGSU UNIVERSITY OF SCIENCE AND TECHNOLOGY(NATURAL SCIENCE EDITION)
2014年
5期
451-455
,共5页
马哲树%范如花%刘少俊%刘炳霞
馬哲樹%範如花%劉少俊%劉炳霞
마철수%범여화%류소준%류병하
SCR催化剂%单孔道%Eley-Rideal动力学%数值模拟
SCR催化劑%單孔道%Eley-Rideal動力學%數值模擬
SCR최화제%단공도%Eley-Rideal동역학%수치모의
SCR catalyst%single channel%Eley-Rideal mechanism%numerical simulation
针对V2 O5/TiO2催化剂建立了三维单孔道模型,基于Eley-Rideal动力学机制,模拟了单孔道内的流动及NOx 在催化剂表面的反应情况.经模拟结果与实验结果对比,证明了模型的合理性.研究表明:随着Re的增大脱硝效率逐渐降低;模拟温度在523~723 K时,反应物NO的转化率随温度先升高后降低;根据NO的转化率及NH3的逃逸率综合考虑NH3/NO摩尔比应该控制在0.9~1.2之间;在温度为598 K, Re 为600, NH3/NO 摩尔比为1时, NO 的转化率最高可达到97.18%;反应物的浓度沿孔道方向先快速下降后平缓下降,在单孔道长度为1000 mm的模型中,在离入口处600 mm时NO脱除率可达到总脱除率的91.2%.模拟结果可为SCR催化剂的运行优化提供重要依据.
針對V2 O5/TiO2催化劑建立瞭三維單孔道模型,基于Eley-Rideal動力學機製,模擬瞭單孔道內的流動及NOx 在催化劑錶麵的反應情況.經模擬結果與實驗結果對比,證明瞭模型的閤理性.研究錶明:隨著Re的增大脫硝效率逐漸降低;模擬溫度在523~723 K時,反應物NO的轉化率隨溫度先升高後降低;根據NO的轉化率及NH3的逃逸率綜閤攷慮NH3/NO摩爾比應該控製在0.9~1.2之間;在溫度為598 K, Re 為600, NH3/NO 摩爾比為1時, NO 的轉化率最高可達到97.18%;反應物的濃度沿孔道方嚮先快速下降後平緩下降,在單孔道長度為1000 mm的模型中,在離入口處600 mm時NO脫除率可達到總脫除率的91.2%.模擬結果可為SCR催化劑的運行優化提供重要依據.
침대V2 O5/TiO2최화제건립료삼유단공도모형,기우Eley-Rideal동역학궤제,모의료단공도내적류동급NOx 재최화제표면적반응정황.경모의결과여실험결과대비,증명료모형적합이성.연구표명:수착Re적증대탈초효솔축점강저;모의온도재523~723 K시,반응물NO적전화솔수온도선승고후강저;근거NO적전화솔급NH3적도일솔종합고필NH3/NO마이비응해공제재0.9~1.2지간;재온도위598 K, Re 위600, NH3/NO 마이비위1시, NO 적전화솔최고가체도97.18%;반응물적농도연공도방향선쾌속하강후평완하강,재단공도장도위1000 mm적모형중,재리입구처600 mm시NO탈제솔가체도총탈제솔적91.2%.모의결과가위SCR최화제적운행우화제공중요의거.
Based on Eley-Rideal kinetic mechanism, a 3D single channel mathematical model for honeycomb catalyst ( V2 O5/TiO2 ) was established.Flow and reaction coupled process in the catalyst was investigated.The simulation results coincide with the experimental results in literatures, which proves the reliability of the model. The simulation results show that with the increase of Re number, the efficiency of de-NOx gradually decreases. Between 523~723 K, NO conversion rates rise firstly, and then drop.Considering the conversion rates of NO and the escape rates of NH3 , the NH3/NO ratio should be controlled between 0.9~1.2 .According to the calcu-lation results, the de-NOx efficiency can reach 97.18%at 598 K, a Re number of 600 and a NH3/NO molar rati-o of 1.The concentrations of reactants along the axial direction decline sharply and then level off.At a distance of 600 mm from the entrance, the NO removal rate reached 91%of the total one in the 1000 mm length model. The simulation results can provide an important basis for the operation optimization of SCR catalysts.