电子科技大学学报
電子科技大學學報
전자과기대학학보
JOURNAL OF UNIVERSITY OF ELECTRONIC SCIENCE AND TECHNOLOGY OF CHINA
2015年
1期
129-133
,共5页
段成丽%蒋亚东%叶宗标%太惠玲
段成麗%蔣亞東%葉宗標%太惠玲
단성려%장아동%협종표%태혜령
复合%石墨%大应变%多壁碳纳米管%聚二甲基硅氧烷
複閤%石墨%大應變%多壁碳納米管%聚二甲基硅氧烷
복합%석묵%대응변%다벽탄납미관%취이갑기규양완
composite%graphite%large strain%multi-walled carbon nanotubes%polydimethylsiloxane
采用物理共混工艺制备了聚二甲基硅氧烷/多壁碳纳米管(PDMS/MWNTs)复合大应变敏感材料,研究了掺杂比例对其大应变敏感特性的影响;在形貌表征基础上建立了敏感机理模型。初步探索了MWNTs和石墨填充PDMS复合材料的大应变特性。结果表明,PDMS/MWNTs复合材料相对电阻变化率与大应变成良好的线性特性,其中MWNTs掺量为9 wt%时复合材料表现出最优的应变特性,应变系数达到3.1;MWNTs和石墨填充PDMS复合材料电阻变化随大应变表现出非线性特性,分析认为MWNTs的远程导电网络和石墨的近程导电网络相互补充,搭建起更加稳定的导电通路,从而减缓了电阻的线性增大。
採用物理共混工藝製備瞭聚二甲基硅氧烷/多壁碳納米管(PDMS/MWNTs)複閤大應變敏感材料,研究瞭摻雜比例對其大應變敏感特性的影響;在形貌錶徵基礎上建立瞭敏感機理模型。初步探索瞭MWNTs和石墨填充PDMS複閤材料的大應變特性。結果錶明,PDMS/MWNTs複閤材料相對電阻變化率與大應變成良好的線性特性,其中MWNTs摻量為9 wt%時複閤材料錶現齣最優的應變特性,應變繫數達到3.1;MWNTs和石墨填充PDMS複閤材料電阻變化隨大應變錶現齣非線性特性,分析認為MWNTs的遠程導電網絡和石墨的近程導電網絡相互補充,搭建起更加穩定的導電通路,從而減緩瞭電阻的線性增大。
채용물리공혼공예제비료취이갑기규양완/다벽탄납미관(PDMS/MWNTs)복합대응변민감재료,연구료참잡비례대기대응변민감특성적영향;재형모표정기출상건립료민감궤리모형。초보탐색료MWNTs화석묵전충PDMS복합재료적대응변특성。결과표명,PDMS/MWNTs복합재료상대전조변화솔여대응변성량호적선성특성,기중MWNTs참량위9 wt%시복합재료표현출최우적응변특성,응변계수체도3.1;MWNTs화석묵전충PDMS복합재료전조변화수대응변표현출비선성특성,분석인위MWNTs적원정도전망락화석묵적근정도전망락상호보충,탑건기경가은정적도전통로,종이감완료전조적선성증대。
The PDMS/MWNTs (polydimethylsiloxane/multi-walled carbon nanotubes) composite large strain sensitive materials were prepared by the physical blending technology, and the effect of the proportion on the large strain sensing properties was investigated. The sensing mechanism model was established based on the microstructures characterization. The large strain properties of PDMS composite material filled with MWNTs and graphite were preliminary explored. The results show that the PDMS/MWNTs composite material exhibits the good linear characteristic between the relative resistance rate and the large strain:the optimal strain property with the strain coefficient 3.1 can be obtained when the content of MWNTs is 9 wt %. The resistance change of the PDMS/MWNTs/graphite composite materials exhibits the nonlinear characteristics with the large strain. The analysis reveals that the mutual complementation of the remote conductive network of MWNTs and short-range conductive network of graphite forms the more stable conductive pathways and network, so as to retard the linear increase of resistance.